Visible-Light-Mediated Synthesis of Thioesters Using Thiocarboxylic Acid as the Dual Reagent

We have developed a visible-light-driven method for thioester synthesis that relies on the unique dual role of thiobenzoic acids as one-electron reducing agents and reactants leading to the formation of sulfur radical species. This synthetic process offers a wide scope, accommodating various thioaci...

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Bibliographic Details
Published in:Journal of organic chemistry 2024-04, Vol.89 (7), p.4607-4618
Main Authors: Bhat, Muneer-ul-Shafi, Ganie, Majid Ahmad, Kumar, Sourav, Rizvi, Masood Ahmad, Raheem, Shabnam, Shah, Bhahwal Ali
Format: Article
Language:English
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Summary:We have developed a visible-light-driven method for thioester synthesis that relies on the unique dual role of thiobenzoic acids as one-electron reducing agents and reactants leading to the formation of sulfur radical species. This synthetic process offers a wide scope, accommodating various thioacid and thiol substrates without the need for a photocatalyst.
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.3c02877