Transient heat, mass and momentum transfer of an evaporating stationary droplet containing dissolved cerium nitrate in a rf thermal argon–oxygen plasma under reduced pressure

• Published in: International journal of heat and mass transfer 2007, Vol.50 (1), p.240-256
• Main Authors: Castillo, I., Munz, R.J.
• Format: Article
• Language: English
• Subjects: ALE; Evaporation; Solid oxide fuel cells; Solution droplets; Thermal plasma
• ISSN: 0017-9310; 1879-2189
• DOI: 10.1016/j.ijheatmasstransfer.2006.06.023

Heat and mass transfer effects in evaporating solution droplets (20–40 μm in diameter) containing dissolved hexahydrated cerium nitrate in a stationary rf Ar–O 2 thermal plasma were investigated using a model. The evaporation occurred under reduced pressure. The impact of different plasma operating parameters on temperature and dissolved solid content profiles was studied: surrounding plasma temperature, initial salt content and droplet size, plasma gas composition, and system pressure. Temperature and composition dependant thermophysical properties were used. The model was solved in a moving frame (ALE method) and considered Stefan flow. The results indicate that a salt supersaturation limit is reached at the droplet surface which leads to salt precipitation and formation of a crust in all cases analyzed. This is favored by higher plasma temperatures, lower pressures, oxygen-rich plasma and higher salt content. Smaller droplets developed a crust faster than larger droplets.