Wear resistant and anti-corrosive treatment for TI–6AL–4V using metal vapor vacuum arc source in comparison with plasma immersion ion implantation

• Published in: Thin solid films 2006-09, Vol.515 (1), p.122-128
• Main Authors: Chang, Chia-Wei, Liao, Jiunn-Der, Chen, Huan-Jen, Chang, Charlie S.F., Chiu, Song-Mao
• Format: Article
• Language: English
• Subjects: Anticorrosive; Applied sciences; Condensed matter: structure, mechanical and thermal properties; Contact of materials. Friction. Wear; Corrosion; Corrosion mechanisms; Defects and impurities in crystals; microstructure; Exact sciences and technology; Mechanical and acoustical properties of condensed matter; Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology; Mechanical properties of solids; Metal vapor vacuum arc; Metals. Metallurgy; Nano Vision; Nanoindentation; Physics; Plasma immersion ion implantation; Point defects (vacancies, interstitials, color centers, etc.) and defect clusters; Structure of solids and liquids; crystallography; Tribology and hardness
• ISSN: 0040-6090; 1879-2731
• DOI: 10.1016/j.tsf.2005.12.047

This study utilizes two ion-implantation methods, plasma immersion ion implantation (PIII) and metal vapor vacuum arc (MeVVA), to prepare Ti–N phases on the surface of Ti–6Al–4V. By the nitrogen PIII method, both nitrogen and minor oxygen species are simultaneously attracted by the negatively charged substrate. The penetration of N and O interstitial elements to an extensible depth is possible owing to the effect from the negatively charged target. The nitrogen PIII treatment does not produce a novel Ti–N phase. As a result, the modified surface does not behave anticorrosive. The H n and the E determined by nanoindentation also remain unchanged. It is still potential to apply this non-directional treatment by increasing bias voltage of the target, coating pure titanium on Ti–6Al–4V, and adjusting the regeneration process of nitrogen ions. The MeVVA treatment creates a novel αTiN 0.3 (011) phase on Ti–6Al–4V in present study. It signifies that the interactions between kinetic Ti ions of varied energies and minor nitrogen molecules, with minor participation of oxygen, are highly feasible. The novel ion-implanted Ti–N phase is corrosion resistant, which is capable to reduce passivation current density by forming a passive film. Moreover, the MeVVA-treated surface is surface-hardened; the E is simultaneously increased. The increase of nano mechanical properties can be visualized by 3D images using Nano Vision and determined by analyzing the tip/surface impact structure on the indentation site.