Influence of porosity and composition of porous carriers on the uptake of nutrients

• Published in: Water science and technology 2003-01, Vol.48 (3), p.105-112
• Main Authors: KHELIFI, O, KOZUKI, Y, MURAKAMI, H, KURATA, K, KONO, Y
• Format: Article
• Language: English
• Subjects: Ammonia - isolation & purification; Ammonium; Applied sciences; Aquatic environment; Bioreactors; Blast furnace practice; Blast furnace slags; Compressive strength; Current carriers; Exact sciences and technology; Fly ash; Heavy metals; Industrial Waste; Industrial wastes; Metal concentrations; Natural water pollution; Nitrogen - isolation & purification; Nutrient uptake; Nutrients; Other industrial wastes. Sewage sludge; Phosphorus - isolation & purification; Pollution; Porosity; Seawater; Seawaters, estuaries; Slag; Solid wastes; Temperature; Wastes; Water Pollutants - isolation & purification; Water Purification - methods; Water treatment and pollution; Zeolites - chemistry
• ISSN: 0273-1223; 1996-9732
• DOI: 10.2166/wst.2003.0174

The current paper assesses the potential of industrial solid wastes utilization such as blast furnace slag (BFS) and zeolite synthesized from fly ash (ZFA), which are effective as well as economically attractive for the uptake of phosphate and ammonium from polluted seawater. The solidification of BFS and ZFA has been developed in different proportions of BFS/ZFA (30/70, 50/50 and 70/30 (w/w)) with different porosities (25%, 40% and 52%, respectively) to cylindrical porous carriers using a Hydrothermal Hot-Pressing (HHP) method. The concentrations of heavy metals in ZFA and BFS were too low to affect the aquatic environment. The main finding is that the high rate of BFS (70%) in porous carriers enhanced phosphate uptake explained by the higher percentage of calcium (35.7%) in porous carriers and high pH conditions. The efficient ammonium uptake was observed with high rate of ZFA (70%) in porous carriers. Results found through this experimental work imply that porous carriers with BFS/ZFA proportion of 70/30 are suitable for potential practical application in the aquatic environment due to their efficient uptake of phosphate and ammonium. The choice was made upon their porosity (40%) and their compressive strength (56 kgf/cm2) which are relatively higher than those with BFS/ZFA proportion of 30/70 and 50/50.