Cyanuric Acid and Melamine on Au(111): Structure and Energetics of Hydrogen-Bonded Networks

Expect the unexpected: The interaction between cyanuric acid (CA) and melamine (M) molecules is a key structural motif in supramolecular chemistry. The adsorption and coadsorption of M and CA on a Au(111) surface under ultrahigh vacuum (UHV) is investigated using STM with submolecular resolution (se...

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Published in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2007-05, Vol.3 (5), p.854-858
Main Authors: Xu, Wei, Dong, Mingdong, Gersen, Henkjan, Rauls, Eva, Vázquez-Campos, Socorro, Crego-Calama, Mercedes, Reinhoudt, David N., Stensgaard, Ivan, Laegsgaard, Erik, Linderoth, Trolle R., Besenbacher, Flemming
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Language:English
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hydrogen bonding
molecular recognition
nanotechnology
scanning probe microscopy
supramolecular chemistry
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creator Xu, Wei
Dong, Mingdong
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Rauls, Eva
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Laegsgaard, Erik
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description Expect the unexpected: The interaction between cyanuric acid (CA) and melamine (M) molecules is a key structural motif in supramolecular chemistry. The adsorption and coadsorption of M and CA on a Au(111) surface under ultrahigh vacuum (UHV) is investigated using STM with submolecular resolution (see image). In addition to the expected structure with a 1:1 CA/M ratio, a novel phase with a 1:3 CA/M forms upon sequential deposition.
doi_str_mv 10.1002/smll.200600407
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subjects hydrogen bonding
molecular recognition
nanotechnology
scanning probe microscopy
supramolecular chemistry
title Cyanuric Acid and Melamine on Au(111): Structure and Energetics of Hydrogen-Bonded Networks
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