Epoxidation of cyclooctene with hydroperoxy sultams catalyzed by molybdenum boride

The hydroperoxy sultams have been investigated in epoxidation reaction of cyclooctene catalyzed by MoB. It was shown hydroperoxides can function as the epoxidation agents. The high epoxides yields were observed in the case of hydroperoxy sultams with chlorine atoms. ▪ The hydroperoxy sultams (HPS) h...

Full description

Saved in:
Bibliographic Details
Published in:Applied catalysis. A, General General, 2007-04, Vol.323, p.174-180
Main Authors: Makota, O., Wolf, J., Trach, Yu, Schulze, B.
Format: Article
Language:English
Subjects:
Catalysis
Catalyst
Chemistry
Epoxidation
Exact sciences and technology
General and physical chemistry
Hydroperoxide
Hydroperoxy sultam
Molybdenum boride
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The hydroperoxy sultams have been investigated in epoxidation reaction of cyclooctene catalyzed by MoB. It was shown hydroperoxides can function as the epoxidation agents. The high epoxides yields were observed in the case of hydroperoxy sultams with chlorine atoms. ▪ The hydroperoxy sultams (HPS) have been investigated in catalytic epoxidation reaction of cyclooctene. We have found that HPS can function as the epoxidation agents in the presence of molybdenum boride MoB as a catalyst. The reaction was sensitive to steric as well as electronic factors. The high epoxides yields were observed in the case of hydroperoxy sultams with chlorine atoms and especially favorable was hydroperoxide structure with α-position of chlorine atom to bond of nitrogen with aromatic ring.
ISSN:0926-860X
1873-3875
DOI:10.1016/j.apcata.2007.02.013