Properties of Ni/YSZ porous cermets prepared by electroless coating technique for SOFC anode application

• Published in: Journal of materials science 2007-09, Vol.42 (17), p.7220-7226
• Main Authors: Pratihar, Swadesh K, Dassharma, A, Maiti, H. S
• Format: Article
• Language: English
• Subjects: Anodes; Applied sciences; Building materials. Ceramics. Glasses; Ceramic industries; Cermets; Cermets, ceramic and refractory composites; Chemical industry and chemicals; coatings; Cross-disciplinary physics: materials science; rheology; Electrical resistivity; electrodes; Electroless coating; Electrotechnical and electronic ceramics; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Materials science; Nickel; Other materials; Physics; pressing; Resistivity; Sintering (powder metallurgy); soaking; Solid oxide fuel cells; Specific materials; Technical ceramics; temperature; Thermal expansion; Yttria stabilized zirconia; Yttrium oxide; Zirconium dioxide
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-007-1497-x

A conceptual nickel–yttria stabilized zirconia (Ni/YSZ) cermet has been prepared by coating YSZ particles with metallic nickel using electroless coating technique. Concentration of nickel was varied between 5 and 60 vol%. Bulk samples were prepared by uniaxial pressing followed by sintering in the temperature range 1,200–1,350 °C with a soaking time of 2–6 h. Thorough investigation on the electrical characteristics, thermal expansion behavior of the samples have been performed as a function of Ni-content in the cermet. Thermal expansion behavior and conductivity measurement results suggest that the samples prepared by this technique are suitable for solid oxide fuel cell (SOFC) anode application at Ni concentration as low as 20 vol%.