A dynamic covalent approach to [PtnL2n]2n+ cages

A dynamic covalent approach was exploited to generate a family of homometallic [PtnL2n]2n+ cage (predominantly [Pt2L4]4+ systems) architectures. The family of platinum(ii) architectures were characterized using 1H nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (DOSY), electrospr...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-04, Vol.60 (32), p.4302-4305
Main Authors: Quinn V C van Hilst, Pearcy, Aston C, Preston, Dan, Wright, L James, Hartinger, Christian G, Brooks, Heather J L, Crowley, James D
Format: Article
Language:English
Subjects:
Cages
Crystallography
Mass spectrometry
Molecular structure
NMR
Nuclear magnetic resonance
Online Access:Get full text
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Summary:A dynamic covalent approach was exploited to generate a family of homometallic [PtnL2n]2n+ cage (predominantly [Pt2L4]4+ systems) architectures. The family of platinum(ii) architectures were characterized using 1H nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (DOSY), electrospray ionization mass spectrometry (ESI-MS) and the molecular structures of two cages were determined by X-ray crystallography.
ISSN:1359-7345
1364-548X
DOI:10.1039/d4cc00323c