Two step sol-gel processing of TEOS based hydrophobic silica aerogels using trimethylethoxysilane as a co-precursor

• Published in: Journal of porous materials 2007-06, Vol.14 (2), p.165-171
• Main Authors: Hegde, Nagaraja D., Hirashima, Hiroshi, Venkateswara Rao, A.
• Format: Article
• Language: English
• Subjects: Contact angle; Fourier transforms
• ISSN: 1380-2224; 1573-4854
• DOI: 10.1007/s10934-006-9021-2

The experimental results on the surface modification of tetraethoxysilane (TEOS) based silica aerogels using trimethylethoxysilane (TMES) as a co-precursor by two step sol-gel process are reported. The molar ratio of MeOH/TEOS was fixed at 17 and TMES/TEOS ratio was varied from 0.38 to 1.14. The concentration and quantity of acidic water (oxalic acid) added in the first step and base water (ammonium hydroxide) in the second step were also varied. The best quality superhydrophobic aerogels could be obtained with only distilled water (without any acid catalyst) in the first stage and the basic water in the second step of the sol-gel process. The molar ratio of TEOS: TMES: MeOH: distilled water: basic water was optimized at 1:0.86:17:4.9:4.9, respectively. The surface modification has been confirmed from the Fourier transform infrared spectroscopy measurements while the hydrophobicity was quantified in terms of the contact angle measurements. The TMES/TEOS based aerogel powder could be used to transport micro-liters of water in the form of water marbles. The aerogels have been characterized by the bulk density, porosity, thermal conductivity, contact angle measurements and the transmission electron microscopy (TEM).[PUBLICATION ABSTRACT]