Preparation and polymerization of bismaleimide compounds

Bismaleimides with main chains of different structures were prepared by the reaction between maleic anhydride and various diamines and by the reaction between 4-maleimidobenzoylchloride and 3,5-dihidroxybenzoic acid. The monomers were characterized with IR and ¹H-NMR spectroscopy. Polymers based on...

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Bibliographic Details
Published in:Journal of applied polymer science 2007-11, Vol.106 (4), p.2185-2191
Main Authors: Sava, M, Sava, I, Cozan, V, Tanasa, F
Format: Article
Language:English
Subjects:
Applied sciences
Chemical properties
Exact sciences and technology
infrared spectroscopy
NMR
Polymer industry, paints, wood
Properties and testing
structure-property relations
synthesis
Technology of polymers
thermal properties
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Summary:Bismaleimides with main chains of different structures were prepared by the reaction between maleic anhydride and various diamines and by the reaction between 4-maleimidobenzoylchloride and 3,5-dihidroxybenzoic acid. The monomers were characterized with IR and ¹H-NMR spectroscopy. Polymers based on these compounds were prepared through the Michael addition of diamines to bismaleimides. The thermal characterization of the monomers and polymers was performed with differential scanning calorimetry and dynamic thermogravimetric analysis. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007
ISSN:0021-8995
1097-4628
DOI:10.1002/app.26739