Intramolecular Singlet Fission Coupled with Intermolecular Triplet Separation as a Strategy to Achieve High Triplet Yields in Fluorene-Based Small Molecules

• Published in: The journal of physical chemistry. B 2024-04, Vol.128 (14), p.3442-3453
• Main Authors: Mencaroni, Letizia, Elisei, Fausto, Marrocchi, Assunta, Spalletti, Anna, Carlotti, Benedetta
• Format: Article
• Language: English
• Subjects: B: Liquids; Chemical and Dynamical Processes in Solution
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/acs.jpcb.4c00194

In this work, detailed experimental proof and in-depth analysis of the singlet fission (SF) mechanism, operative in fluorene-based small molecules, are carried out by employing advanced time-resolved spectroscopies with nanosecond and femtosecond resolution. The investigation of the effect of solution concentration and solvent viscosity together with temperature and excitation wavelength demonstrates INTRAmolecular formation of the correlated triplet pair followed by INTERmolecular independent triplet separation via a “super-diffusional” triplet–triplet transfer process. This unconventional INTRA- to INTERmolecular SF may be considered an “ideal” mechanism. Indeed, intramolecular formation of the correlated triplet pair is here interestingly proved for small molecules rather than large multichromophoric systems, allowing easy synthesis and processability while maintaining good control over the SF process. On the other hand, the intermolecular triplet separation may be exploited to achieve high triplet quantum yields in these new SF small molecules.