Photothermal Performance of Lignin-Based Nanospheres and Their Applications in Water Surface Actuators

• Published in: Polymers 2024-04, Vol.16 (7), p.927
• Main Authors: Wen, Mingshan, Wang, Hang, Ma, Bole, Xiong, Fuquan
• Format: Article
• Language: English
• Subjects: Actuation; Actuators; Carbon; Contact angle; Curing; Efficiency; Energy; Epoxy resins; Ethanol; Filter paper; Force and energy; Hydrophobic surfaces; Hydrophobicity; Investigations; Light irradiation; Lignin; Microfluidics; Molecular weight; Nanospheres; Photothermal conversion; Room temperature; Spectrum analysis; Substrates
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym16070927

In this study, the photothermal performance of lignin-based nanospheres was investigated. Subsequently, a photothermal actuator was prepared using lignin-based carbon nanospheres (LCNSs). The results demonstrated that LCNSs exhibited an impressive photothermal conversion efficiency of up to 83.8%. This extreme efficiency significantly surpasses that of lignin nanospheres (LNSs) and covalently stabilized LNSs (HT-LNSs). As a structural material, a hydrophobic coating was effectively engineered by LCNSs on the filter paper, achieving a water contact angle of 151.9° ± 4.6°, while maintaining excellent photothermal effects (with a temperature increment from room temperature to 138 °C in 2 s). When employing hydrophobic filter paper as the substrate for the photothermaldriven actuator, under the influence of a 1.0 W/cm power-density NIR laser, the material exhibited outstanding photothermal actuation, achieving speeds up to 16.4 mm/s. In addition, the direction of motion of the actuator can be adjusted in accordance with the location of the NIR light irradiation. This study offers valuable perspectives on the application of LNSs for highvalue applications and the development of innovative photothermal-driven actuators.