The Incorporation of Graphene Nanoplatelets in Tung Oil-Urea Formaldehyde Microcapsules: A Paradigm Shift in Physicochemical Enhancement

• Published in: Polymers 2024-04, Vol.16 (7), p.909
• Main Authors: Mustapha, Abdullah Naseer, AlMheiri, Maitha, AlShehhi, Nujood, Rajput, Nitul, Matouk, Zineb, Tomić, Nataša
• Format: Article
• Language: English
• Subjects: Addition polymerization; Additives; Aqueous solutions; Carbon; Corrosion and anti-corrosives; Corrosion resistance; Curing; Electron microscopes; Epoxy coatings; Epoxy resins; Formaldehyde; Gelatin; Graphene; Graphite; Heat conductivity; High resolution electron microscopy; Image enhancement; Interlayers; Investigations; Microencapsulation; Micromanipulation; Morphology; Platelets (materials); Polymerization; Scanning electron microscopy; Spectrum analysis; Substrates; Surface active agents; Synergistic effect; Transmission electron microscopy; Urea; Ureas; Viscosity
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym16070909

Tung oil (TO) microcapsules (MCs) with a poly(urea-formaldehyde) (PUF) shell were synthesized via one-step in situ polymerization, with the addition of graphene nanoplatelets (GNPs) (1-5 wt. %). The synergistic effects of emulsifiers between gelatin (gel) and Tween 80 were observed, with gel chosen to formulate the MCs due to its enhanced droplet stability. SEM images then displayed an increased shell roughness of the TO-GNP MCs in comparison to the pure TO MCs due to the GNP species on the shell. At the same time, high-resolution transmission electron microscopy (TEM) images also confirmed the presence of GNPs on the outer layer of the MCs, with the stacked graphene layers composed of 5-7 layers with an interlayer distance of ~0.37 nm. Cross-sectional TEM imaging of the MCs also confirmed the successful encapsulation of the GNPs in the core of the MCs. Micromanipulation measurements displayed that the 5% GNPs increased the toughness by 71% compared to the pure TO MCs, due to the reduction in the fractional free volume of the core material. When the MCs were dispersed in an epoxy coating and applied on a metallic substrate, excellent healing capacities of up to 93% were observed for the 5% GNP samples, and 87% for the pure TO MC coatings. The coatings also exhibited excellent corrosion resistance for all samples up to 7 days, with the GNP samples offering a more strenuous path for the corrosive agents.