Semi-continuous hydrothermal processing of pine sawdust for integrated production of fuels precursors and platform chemicals

• Published in: The Science of the total environment 2024-02, Vol.912, p.169168-169168, Article 169168
• Main Authors: Puhl, Bruna A., Draszewski, Crisleine P., Vezaro, Francisco D., Ten Caten, Leonardo R., Wancura, João H.C., de Castilhos, Fernanda, Mayer, Flávio D., Abaide, Ederson R.
• Format: Article
• Language: English
• Subjects: arabinose; Bio-char; Bio-crude; biofuels; Biomass; cellobiose; environment; furfural; glucose; Hydrothermal liquefaction; hydroxymethylfurfural; levulinic acid; sawdust; Subcritical hydrolysis; temperature; wood; xylose
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2023.169168

This research reports data for the integrated obtaining of fermentable sugars (FSs), bio-oil (BO), and hydro-char (HC) – all fuel precursors – as well as platform chemicals (PCs – acetic, formic, and levulinic acid, besides furfural, and hydroxymethylfurfural) through semi-continuous hydrothermal processing of sawdust from pine wood. The influence of temperature (260, 300, and 340 °C) and the water-to-biomass ratio (25 and 50 g H2O (g biomass)−1) were the parameters considered to evaluate the mass yields, kinetic profiles, and BO properties. For FSs (and PCs), a detailed analysis considering the kinetic profiles of obtaining cellobiose, glucose, xylose, and arabinose is presented. For the conditions evaluated, a distinct behavior concerning the process parameters was observed, where 7.11 and 9.28 g (100 g biomass)−1 of FSs and PCs were synergistically obtained, respectively, after 30 min, 20 MPa, 260 °C, and 50 g H2O (g biomass)−1. Contextually, 17.59 g (100 g biomass)−1 of BO was obtained at 340 °C and the same water/biomass ratio. FTIR analysis of the BO samples suggested the presence of aldehydes, carboxylic acids, ketones, hydrocarbons, ethers as well as aromatic, alcohols, and nitrogenous compounds. Similar HC yields were achieved among the conditions analyzed, where 24.68 g (100 g biomass)−1 were obtained at 340 °C and 50 g H2O (g biomass)−1 for a higher heating value of 29.14 MJ kg−1 (1.5 times higher than the in natura biomass). [Display omitted] •Novel semi-continuous hydrothermal processing configuration of pine sawdust is addressed.•Fuel precursors (fermentable sugars, bio-oil, and hydro-char) are produced concomitantly.•Platform chemicals (organic acids, furfural, and HMF) were also concurrently synthesized.•The semi-continuous configuration allowed generating kinetic profiles of the compounds.•Control temperature and water flow guided the process towards the desired product formation.