Magnetic ionic crystals with light controllable mobility and CO2 physisorption/desorption

Magnetic responsive ionic liquid (MIL) demonstrated an advanced photomobility in confined narrow spaces through the doping of photoresponsive azobenzene by the interplay of supramolecular π–cations. Moreover, reversible physisorption/desorption of CO2 was achieved based on the photocontrolled solid–...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-05, Vol.60 (39), p.5165-5168
Main Authors: Ge, Yifan, Tan, Shuai, Wu, Yong, Wang, Caihong
Format: Article
Language:English
Subjects:
Azo compounds
Carbon dioxide
Controllability
Desorption
Ionic crystals
Ionic liquids
Online Access:Get full text
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Summary:Magnetic responsive ionic liquid (MIL) demonstrated an advanced photomobility in confined narrow spaces through the doping of photoresponsive azobenzene by the interplay of supramolecular π–cations. Moreover, reversible physisorption/desorption of CO2 was achieved based on the photocontrolled solid–liquid transitions of the mixtures. Our approach opens opportunities to obtain multi-stimuli response through the coordinated supramolecular interplay of each responsive component.
ISSN:1359-7345
1364-548X
DOI:10.1039/d4cc00301b