Poly[3-methyl-pyridinium [(μ2-di-hydrogen phosphito)bis(μ3-hydrogen phosphito)dizinc]]

In the title compound, {(C6H8N)[Zn2(HPO3)2(H2PO3)]}n, the constituent ZnO4, HPO3 and H2PO3 polyhedra of the inorganic component are linked into (010) sheets by Zn-O-P bonds (mean angle = 134.4°) and the layers are reinforced by O-H⋯O hydrogen bonds. The protonated templates are anchored to the inorg...

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Bibliographic Details
Published in:IUCrData 2024-04, Vol.9, p.x240345-x240345
Main Authors: Love-Jennings, Jago G, McKay, Aidan P, Cordes, David B, Harrison, William T A
Format: Article
Language:English
Online Access:Get full text
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Summary:In the title compound, {(C6H8N)[Zn2(HPO3)2(H2PO3)]}n, the constituent ZnO4, HPO3 and H2PO3 polyhedra of the inorganic component are linked into (010) sheets by Zn-O-P bonds (mean angle = 134.4°) and the layers are reinforced by O-H⋯O hydrogen bonds. The protonated templates are anchored to the inorganic sheets via bifurcated N-H⋯(O,O) hydrogen bonds.
ISSN:2414-3146
DOI:10.1107/S2414314624003456