Innovative Thermocatalytic H2 Sensor with Double-Sided Pd Nanocluster Films on an Ultrathin Mica Substrate

• Published in: ACS sensors 2024-05, Vol.9 (5), p.2529-2539
• Main Authors: Xie, Bo, Liu, Yini, Lei, Yingshuang, Qian, Haoyu, Li, Yingzhu, Yan, Wenjing, Zhou, Changjiang, Wen, Hui-Min, Xia, Shengjie, Mao, Peng, Han, Min, Hu, Jun
• Format: Article
• Language: English
• ISSN: 2379-3694; 2379-3694
• DOI: 10.1021/acssensors.4c00269

Hydrogen (H2) is crucial in the future global energy landscape due to its eco-friendly properties, but its flammability requires precise monitoring. This study introduces an innovative thermocatalytic H2 sensor utilizing ultrathin mica sheets as substrates, coated on both sides with Pd nanocluster (NC) films. The ultrathin mica substrate ensures robustness and flexibility, enabling the sensor to withstand high temperatures and mechanical deformation. Additionally, it simplifies the fabrication process by eliminating the need for complex microelectro-mechanical systems (MEMS) technology. Constructed through cluster beam deposition, the sensor exhibits exceptional characteristics, including a wide concentration range (from 500 ppm to 4%), rapid response and recovery times (3.1 and 2.4 s for 1% H2), good selectivity, high stability, and repeatability. The operating temperature can be as low as 40 °C, achieving remarkably low power consumption. The study explores the impact of double-sided versus single-sided catalytic layers, revealing significantly higher sensitivity and response with the double-sided configuration due to the increased catalytic surface area. Additionally, the research investigates the relationship between the deposition amount of Pd NCs and the sensor’s sensitivity, identifying an optimal value that maximizes performance without excessive use of Pd. The sensor’s innovative design and excellent performance position it as a promising candidate for meeting the demands of a hydrogen-based energy economy.