Semiconductive Behavior and Photoconductivity of Uranyl Dithiophosphinate Single Crystal

Herein, we detail the synthesis, structure, and photoconductivity of the uranyl dithiophosphinate single crystal UO2[S2P­(C6H5)2]2(CH3OH)·CH3OH (denoted as U-DPDPP). The formation of bonds between uranyl ions and sulfur-based ligands endows U-DPDPP with a distinct electronic absorption property with...

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Published in:Inorganic chemistry 2024-05, Vol.63 (21), p.9706-9710
Main Authors: Wang, Junren, Yang, Liangwei, Yin, Dingrui, Gao, Xudong, Dai, Xing, Li, Kai, Wang, Shuao, Wang, Yaxing
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container_end_page 9710
container_issue 21
container_start_page 9706
container_title Inorganic chemistry
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creator Wang, Junren
Yang, Liangwei
Yin, Dingrui
Gao, Xudong
Dai, Xing
Li, Kai
Wang, Shuao
Wang, Yaxing
description Herein, we detail the synthesis, structure, and photoconductivity of the uranyl dithiophosphinate single crystal UO2[S2P­(C6H5)2]2(CH3OH)·CH3OH (denoted as U-DPDPP). The formation of bonds between uranyl ions and sulfur-based ligands endows U-DPDPP with a distinct electronic absorption property with a broadband spectrum spanning from 250 to 550 nm, giving rise to a unique semiconductive property. Under X-ray illumination, U-DPDPP displays a distinctive photoconductivity response, with a charge carrier mobility lifetime (μτ) of 2.78 × 10–4 cm2·V–1 achieved, which contradicts the electronic-silence behavior of uranyl nitrate crystal.
doi_str_mv 10.1021/acs.inorgchem.4c00801
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title Semiconductive Behavior and Photoconductivity of Uranyl Dithiophosphinate Single Crystal
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