Selective oxidation behavior based on iron-doped MOF derived carbon-based catalysts: Active site regulation and degradation mechanism analysis

• Published in: Journal of colloid and interface science 2024-09, Vol.670, p.323-336
• Main Authors: Chen, Zhonglin, Wang, Xinhao, Zhang, Ming, Liu, Chenyong, Li, Wenhui, Tian, Tian, Wei, Wenxian, Qiao, Weichuan, Gu, Cheng, Li, Jiansheng
• Format: Article
• Language: English
• Subjects: Active sites; Degradation mechanism; Reactive oxygen species; Selective removal; Specificity of catalysts
• ISSN: 0021-9797; 1095-7103; 1095-7103
• DOI: 10.1016/j.jcis.2024.05.035

[Display omitted] •Control of ROS types and ratios based on catalyst structure and component modulation.•Selective degradation of pollutants according to the ratio of different ROSs in the system.•Abundant large pores and open channels are created by confined expansion pore-making strategy.•Possible degradation pathways were proposed by DFT calculations and LC-MS. Selective removal of target organic pollutants in complex water quality of municipal sewage is extremely important for the deep treatment of water quality. Here, energetic MOF and Fe-MOF are doped in electrostatic spinning process to adjust the structure and composition of the catalysts, active oxygen species (ROSs), realizing the selective removal of organic pollutants. Non-azo and azo pollutants are selected as target pollutants. Catalysts PCFe-8 with Fe nanoclusters, EPCFe-8 with Fe-Nx, and EPC-8 without Fe doping are used to activate peroxymonosulfate (PMS) for degrading pollutants. The results show that the PCFe-8/PMS system can produce the most SO4− and exhibit superior removal of azo pollutants, whereas the degradation behavior of non-azo pollutants is more inclined to occur in the EPCFe-8/PMS system and the EPC-8/PMS system. This work provides a reference for elucidating the relationship between catalyst structure and components, types of ROSs, and selective degradation of pollutants.