A metal and a metalloid Lewis acid bridged by a μ2-phosphinidene

Dinuclear phosphinidene complexes bridging two transition metal centres are now well established. However, a phosphinidene bridging a metal centre and a main group Lewis acid has not yet been reported. Herein, we describe the generation of a highly reactive phosphinidene complex bridging a tungsten...

Full description

Saved in:
Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2024-06, Vol.53 (23), p.9670-9674
Main Authors: Biskup, David, Schnakenburg, Gregor, Arturo Espinosa Ferao, Streubel, Rainer
Format: Article
Language:English
Subjects:
Lewis acid
Transition metals
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Dinuclear phosphinidene complexes bridging two transition metal centres are now well established. However, a phosphinidene bridging a metal centre and a main group Lewis acid has not yet been reported. Herein, we describe the generation of a highly reactive phosphinidene complex bridging a tungsten and a boron centre. Furthermore, the synthesis and dyotropic rearrangement of a P-borane adduct of an N-methylimidazole-stabilized neutral, electrophilic terminal phosphinidene complex is reported.
ISSN:1477-9226
1477-9234
DOI:10.1039/d4dt01276c