Quaternized chitosan/polyvinyl alcohol anion exchange membrane enhanced by functionalized attapulgite clay with an ionic “chain-ball” surface structure

• Published in: International journal of biological macromolecules 2024-06, Vol.271 (Pt 1), p.132595, Article 132595
• Main Authors: Deng, Bangjun, Gong, Chunli, Wen, Sheng, Liu, Hai, Zhang, Xiaowen, Fan, Xiangjian, Wang, Fei, Guo, Li, Xiong, Zemiao, Du, Feipeng, Ou, Ying
• Format: Article
• Language: English
• Subjects: Anion exchange membrane; Anions - chemistry; Chitosan; Chitosan - chemistry; Clay - chemistry; Functionalized attapulgite; Ion Exchange; Magnesium Compounds - chemistry; Membranes, Artificial; Polyvinyl Alcohol - chemistry; Silicon Compounds - chemistry; Surface Properties; Tensile Strength
• ISSN: 0141-8130; 1879-0003; 1879-0003
• DOI: 10.1016/j.ijbiomac.2024.132595

Biomass chitosan has garnered considerable interest for alkaline anion exchange membranes (AEMs) due to its eco-friendly and sustainable characteristics, low reactant permeability and easily modifiable nature, but it still faces the trade-off between high hydroxide conductivity and sufficient mechanical properties. Herein, a novel functionalized attapulgite clay (f-ATP) with a unique ionic “chain-ball” surface structure was prepared and incorporated with quaternized chitosan (QCS)/polyvinyl alcohol (PVA) matrix to fabricate high-performance composite AEMs. Due to the strengthened interfacial bonding between f-ATP nanofillers and the QCS/PVA matrix, composite membranes are synergistically reinforced and toughened, achieving peak tensile strength and elongation at break of 24.62 MPa and 33.8 %. Meanwhile, abundant ion pairs on f-ATP surface facilitate ion transport in the composite AEMs, with the maximum OH− conductivity of 46 mS cm−1 at 80 °C and the highest residual IEC of 83 % after alkaline treatment for 120 h. Moreover, the assembled alkaline direct methanol fuel cell exhibits a remarkable power density of 49.3 mW cm−2 at 80 °C. This work provides a new strategy for fabricating high-performance anion exchange membranes. [Display omitted] •Functionalized attapulgite with an ionic “chain-ball” surface structure was prepared.•The attapulgite was incorporated with quaternized chitosan/polyvinyl alcohol matrix.•Interfacial bonding between the nanofillers and the matrix was strengthened.•Ion pairs on the surface of functionalized attapulgite can facilitate ion transport.•OH− conductivity and mechanical property of the composite membrane were improved.