Carbon-coated silicon/graphite oxide composites as anode materials for highly stable lithium-ion batteries

• Published in: Physical chemistry chemical physics : PCCP 2024-06, Vol.26 (24), p.17292-1732
• Main Authors: Niu, Lujie, Zhang, Rui, Zhang, Qiang, Wang, Dong, Bi, Yanlei, Wen, Guangwu, Qin, Lu-Chang
• Format: Article
• Language: English
• Subjects: Ammonia; Amorphous materials; Anodes; Carbon; Cladding; Composite materials; Electrical resistivity; Electrochemical analysis; Electrode materials; Graphene; Lithium; Lithium-ion batteries; Rechargeable batteries; Silicon; Structural integrity
• ISSN: 1463-9076; 1463-9084; 1463-9084
• DOI: 10.1039/d4cp01424c

Silicon (Si) has been widely investigated as an anode material for lithium-ion batteries (LIBs) due to its high theoretical capacity. However, the huge volume expansion and low electrical conductivity limit its practical application to some extent. Here, we prepared silicon/reduced graphene oxide/amorphous carbon (Si/G/C) anode materials for lithium-ion batteries using a facile synergistic cladding layer. The protective effect of different carbon layers was explored and it was found that ternary composites have excellent electrochemical properties. In this work, the surface of Si was first modified using ammonia, and the positively charged Si was tightly anchored to the graphene sheet layer. In contrast, amorphous carbon was used as a reinforcing coating for further coating to synergistically build up the cladding layer of Si NPs with graphene oxide. The ternary composite (Si/G/C) material greatly ensures the structural integrity of the composites and shows excellent cycling as well as rate performance compared to Si/reduced graphene oxide and Si/carbon composites. For the Si/G/C composite, at a current density of 1 A g −1 , it can be stably cycled over 267 times with 70% capacity retention (only 0.0711% capacity reduction per cycle). The cycling stability of Si materials is greatly enhanced by the introduction of two carbon sources.