Low vaporization enthalpy of modified chitosan hydrogel for high performance solar evaporator

• Published in: Carbohydrate polymers 2024-09, Vol.340, p.122304-122304, Article 122304
• Main Authors: Anukunwithaya, Patsaya, Liu, Nanxue, Liu, Siqi, Thanayupong, Eknarin, Zhou, Lili, Pimpha, Nuttaporn, Min, Jiakang, Chinsirikul, Wannee, Thitsartarn, Warintorn, Koh, J. Justin, He, Chaobin
• Format: Article
• Language: English
• Subjects: Amine; Chitosan; Desalination; Enthalpy reduction; Hydrogen bond; Solar evaporator
• ISSN: 0144-8617; 1879-1344
• DOI: 10.1016/j.carbpol.2024.122304

The high vaporization enthalpy of water attributed to the strong hydrogen bonds between water molecules is limiting the performance of solar evaporators. This work demonstrates a deliberate attempt to significantly reduce the vaporization enthalpy of water through the introduction of weak water-amine hydrogen bond interactions in hydrogel evaporators. In this article, bio-based chitosan-agarose/multiwalled carbon nanotube hydrogel film evaporators (CAMFEs) exhibit larger vaporization enthalpy reduction with the presence of primary amine groups in chitosan. An interplay between vaporization enthalpy reduction and water diffusivity leads to an optimal ratio of chitosan to agarose = 7:1 (CAMFE7) showing an impressive evaporation rate of 4.13 kg m−2 h−1 under 1 sun irradiation. CAMFE7 also exhibits excellent salt resistance, with a stable water evaporation rate, using brine water of up to 10 % salinity under continuous 1 sun irradiation. The high mechanical robustness together with its scalability makes CAMFE7 a highly promising material for practical drinking water production. [Display omitted]