Asymmetric ionic bond shielding encountering with carboxylate capturing metal ions for enhancing the flame retardant durability of regenerated cellulose fibers

• Published in: International journal of biological macromolecules 2024-07, Vol.273 (Pt 2), p.133158, Article 133158
• Main Authors: Liu, Yansong, Chen, Ruixue, Li, Fuqiang, Sun, Ling, Guo, Zengge, Jiang, Zhaohui, Ren, Yuanlin
• Format: Article
• Language: English
• Subjects: Cellulose fibers; Flame retardant; Laundering durability
• ISSN: 0141-8130; 1879-0003; 1879-0003
• DOI: 10.1016/j.ijbiomac.2024.133158

Enhancing the flame retardancy and durability of cellulose fibers, particularly environmentally friendly regenerated cellulose fibers types like Lyocell fibers, is essential for advancing their broader application. This study introduced a novel approach to address this challenge. Cationic-modified Lyocell fibers (Lyocell@CAT) were prepared by introducing quaternary ammonium structures into the molecular chain of Lyocell fibers. Simultaneously, a flame retardant, APA, containing -COO−NH4+ and -P=O(O−NH4+)2 groups was synthesized. APA was then covalently bonded to Lyocell@CAT to prepare Lyocell@CAT@APA. Even after undergoing 30 laundering cycles (LCs), Lyocell@CAT@APA maintained a LOI value of 37.2 %, exhibiting outstanding flame retardant durability. The quaternary ammonium structure within Lyocell@CAT@APA formed asymmetric ionic bonds with the phosphate and carboxylate groups in APA, effectively shielding the binding of Na+ ions with phosphate groups during laundering, thereby enhancing the durability. Additionally, the consumption of Na+ ions by carboxylate groups further prevented their binding to phosphate groups, which contributed to enhance the durability properties. Flame retardant mechanism analysis revealed that both gas and condensed phase synergistically endowed excellent flame retardancy to Lyocell fibers. Overall, this innovative strategy presented a promising prospect for developing bio-safe, durable, and flame retardant cellulose textiles. [Display omitted] •A novel biomass-based flame retardant APA was prepared.•Durable flame-retardant Lyocell fibers were prepared.•The durability was reinforced by asymmetric ionic bond and metal ions capture of carboxylate.•A novel method for enhance the durability of ammonium phosphate flame retardants was proposed.