Unlocking catalytic potential: a rhodium()-based coordination polymer for efficient carbene transfer reactions with donor/acceptor diazoalkanes

Herein, we report the use of a molecular-defined rhodium( ii ) coordination polymer (Rh-CP) as a heterogeneous, recyclable catalyst in carbene transfer reactions. We showcase the application of this heterogeneous catalyst in a range of carbene transfer reactions and conclude with the functionalizati...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-07, Vol.6 (57), p.7327-733
Main Authors: Empel, Claire, Fetzer, Marcus N. A, Sasmal, Suman, Strothmann, Till, Janiak, Christoph, Koenigs, Rene M
Format: Article
Language:English
Subjects:
Carbenes
Catalysts
Coordination polymers
Natural products
Rhodium
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Summary:Herein, we report the use of a molecular-defined rhodium( ii ) coordination polymer (Rh-CP) as a heterogeneous, recyclable catalyst in carbene transfer reactions. We showcase the application of this heterogeneous catalyst in a range of carbene transfer reactions and conclude with the functionalization of natural products and drug molecules. Herein, we report the use of a molecular-defined rhodium( ii ) coordination polymer (Rh-CP) as a heterogeneous, recyclable catalyst in carbene transfer reactions.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc01386g