Voltammetric co-determination of lead and copper in gunshot residue based on iron oxide particle/spent coffee grounds–modified electrode

• Published in: Mikrochimica acta (1966) 2024-07, Vol.191 (7), p.417, Article 417
• Main Authors: Torrarit, Kamonchanok, Cotchim, Suparat, Phonchai, Apichai, Chaisiwamongkhol, Korbua, Limbut, Warakorn
• Format: Article
• Language: English
• Subjects: Analytical Chemistry; Characterization and Evaluation of Materials; Chemical sensors; Chemistry; Chemistry and Materials Science; Coffee; Copper; Electrochemical analysis; Electrochemical impedance spectroscopy; Electrodes; Electron transfer; Electrons; Fourier transforms; Glassy carbon; Inductively coupled plasma; Infrared spectroscopy; Iron oxides; Lead; Microengineering; Nanochemistry; Nanotechnology; Optical emission spectroscopy; Original Paper; Sensors; Voltammetry
• ISSN: 0026-3672; 1436-5073; 1436-5073
• DOI: 10.1007/s00604-024-06481-3

A novel electrochemical sensor was developed for the detection of lead (Pb) and copper (Cu) ions using spent coffee grounds decorated with iron oxide particles (FeO/SCG). The FeO-decorated SCG was used to modify a glassy carbon electrode (GCE). FeO, SCG, and FeO/SCG were characterized by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The electrochemical properties of the modified electrode were characterized by electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The electrode modifications increased the active surface area and electron transfer and enhanced the accumulation of the target analyte. In the optimal condition, the developed sensor showed linear ranges of 1.0 µg L −1 –0.05 mg L −1 and 0.05 mg L −1 –0.8 mg L −1 for Pb 2+ and 5.0 µg L −1 –0.1 mg L −1 and 0.1 mg L −1 –0.8 mg L −1 for Cu 2+ . The limit of detection (LOD) was 1.0 µg L −1 for Pb 2+ and 2.4 µg L −1 for Cu 2+ . The developed sensor was successfully applied to determine Pb 2+ and Cu 2+ in bullet holes. The results were in good agreement with those obtained by inductively coupled plasma optical emission spectrometry (ICP/OES). Graphical abstract