Hemilabile Binding of Acetylene in an Amide-Rich Ultramicroporous MOF Enables Strong Acetylene Selectivity

Thanks to a hemilabile amide-based binding site, a previously unreported amide-functionalized metal–organic framework (MOF) exhibits high acetylene affinity over ethylene, methane, and carbon dioxide, three-in-one.

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Bibliographic Details
Published in:Inorganic chemistry 2024-07, Vol.63 (27), p.12404-12408
Main Authors: Dutta, Subhajit, Mukherjee, Soumya, Javan Nikkhah, Sousa, Qazvini, Omid T., Dam, Gourab K., Vandichel, Matthias, Mandal, Tarak Nath, Ghosh, Sujit K.
Format: Article
Language:English
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Summary:Thanks to a hemilabile amide-based binding site, a previously unreported amide-functionalized metal–organic framework (MOF) exhibits high acetylene affinity over ethylene, methane, and carbon dioxide, three-in-one.
ISSN:0020-1669
1520-510X
1520-510X
DOI:10.1021/acs.inorgchem.4c01933