Advancing Solid Oxide Fuel Cell Performance: Enhanced Electrochemical Properties of Pr1-xCaxBaFe2O5+δ Nanofiber Cathodes via Ca Doping

• Published in: ACS applied materials & interfaces 2024-07, Vol.16 (28), p.36236
• Main Authors: Fu, Xinmin, Meng, Xiangwei, Sun, Chuxiao, Wei, Maobin, Jiang, Haipeng, Lü, Shiquan, Gong, Weijiang
• Format: Article
• Language: English
• ISSN: 1944-8252; 1944-8252
• DOI: 10.1021/acsami.4c03564

The double perovskite oxide PrBaFe2O5+δ has great potential as a cathode material for solid oxide fuel cells (SOFCs). However, the electrochemical characteristics of Fe-based double perovskites are relatively inferior. To improve its electrochemical performance, Ca is investigated to partially replace Pr, forming Pr1-xCaxBaFe2O5+δ (PCBFx, x = 0.0-0.3) by an electrospinning technique. The PCBFx nanofibers exhibited a crystalline structure characterized by orthorhombic symmetry and space group P4/mmm. Furthermore, these PCBFx nanofibers displayed exceptional chemical compatibility with the Sm0.2Ce0.8O1.95 (SDC) electrolyte when sintered at a temperature of 900 °C for 5 h. The X-ray photoelectron spectroscopy (XPS) analysis reveals a progressive increase in the Fe4+ concentration as the Ca doping level rises. The polarization resistances (Rp) of the PCBF00, PCBF01, PCBF02, and PCBF03 nanofiber cathodes were 0.103, 0.079, 0.056, and 0.048 Ω cm2 at 750 °C. In the meantime, doping Ca increases the peak power density of the single cell by 46%, from 762.80 (PCBF00) to 1114.85 (PCBF03) mW cm-2 at 750 °C. The results demonstrate that PCBF03 double perovskite nanofibers exhibit great potential as cathode materials for SOFCs.The double perovskite oxide PrBaFe2O5+δ has great potential as a cathode material for solid oxide fuel cells (SOFCs). However, the electrochemical characteristics of Fe-based double perovskites are relatively inferior. To improve its electrochemical performance, Ca is investigated to partially replace Pr, forming Pr1-xCaxBaFe2O5+δ (PCBFx, x = 0.0-0.3) by an electrospinning technique. The PCBFx nanofibers exhibited a crystalline structure characterized by orthorhombic symmetry and space group P4/mmm. Furthermore, these PCBFx nanofibers displayed exceptional chemical compatibility with the Sm0.2Ce0.8O1.95 (SDC) electrolyte when sintered at a temperature of 900 °C for 5 h. The X-ray photoelectron spectroscopy (XPS) analysis reveals a progressive increase in the Fe4+ concentration as the Ca doping level rises. The polarization resistances (Rp) of the PCBF00, PCBF01, PCBF02, and PCBF03 nanofiber cathodes were 0.103, 0.079, 0.056, and 0.048 Ω cm2 at 750 °C. In the meantime, doping Ca increases the peak power density of the single cell by 46%, from 762.80 (PCBF00) to 1114.85 (PCBF03) mW cm-2 at 750 °C. The results demonstrate that PCBF03 double perovskite nanofibers exhibit great potential as cathode materials for SOFCs.