Visible‐Light‐Induced Multi‐Component Nitrooxylation Reactions of α‐Diazoesters, Cyclic Ethers, and Tert‐Butyl Nitrite Leading to Organic Nitrate Esters

A simple and efficient strategy has been developed for the synthesis of organic nitrate esters via visible‐light‐induced multi‐component nitrooxylation reactions of α‐diazoesters, cyclic ethers, and tert‐butyl nitrite under open air atmosphere. This transformation could be conducted under mild and m...

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Bibliographic Details
Published in:Chemistry : a European journal 2024-10, Vol.30 (57), p.e202402304-n/a
Main Authors: Qian, Cun‐Wei, Li, Xian, Gu, Meng‐Qing
Format: Article
Language:English
Subjects:
Chemical synthesis
Esters
Ethers
Multi-component reaction
Nitrate esters
Nitrates
Nitrooxylation
Oxidants
Oxidizing agents
Visible-light
α-diazoesters
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Summary:A simple and efficient strategy has been developed for the synthesis of organic nitrate esters via visible‐light‐induced multi‐component nitrooxylation reactions of α‐diazoesters, cyclic ethers, and tert‐butyl nitrite under open air atmosphere. This transformation could be conducted under mild and metal‐free conditions to provide a number of organic nitrate esters in moderate to good yields using air as the green oxidant. A mild and facile visible‐light‐promoted multi‐component nitrooxylation reaction of α‐diazoesters, cyclic ethers, and tert‐butyl nitrite leading to organic nitrate esters has been developed at room temperature in air. This multi‐component reaction proceeds smoothly to afford the corresponding organic nitrate esters in moderate to good yields using air the green oxidant.
ISSN:0947-6539
1521-3765
1521-3765
DOI:10.1002/chem.202402304