Azaylide-based gemini amphiphiles displaying unique self-assembling behavior via an even-odd effect of alkyl linker chain length

Herein, we report a straightforward synthesis of azaylide-based gemini amphiphiles using bis(diphenylphosphino)alkanes the Staudinger reaction. The prepared gemini amphiphiles exhibited an even-odd effect in their self-assembly behavior depending on the length of the alkyl linkers. Furthermore, the...

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Bibliographic Details
Published in:Soft matter 2024-08, Vol.20 (33), p.6539-6543
Main Authors: Akiyama, Yoshimori, Yamashina, Masahiro, Toyota, Shinji
Format: Article
Language:English
Subjects:
Alkanes
Chemical synthesis
Hydrophobicity
Micelles
Self-assembly
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Summary:Herein, we report a straightforward synthesis of azaylide-based gemini amphiphiles using bis(diphenylphosphino)alkanes the Staudinger reaction. The prepared gemini amphiphiles exhibited an even-odd effect in their self-assembly behavior depending on the length of the alkyl linkers. Furthermore, the assembled micelles had high host capability toward hydrophobic guests in water.
ISSN:1744-683X
1744-6848
1744-6848
DOI:10.1039/d4sm00789a