Preparation of high quality carbon nanotubes by catalytic pyrolysis of waste plastics using FeNi-based catalyst

• Published in: Waste management (Elmsford) 2024-12, Vol.189, p.11-22
• Main Authors: Meng, Weibo, Xing, Baolin, Cheng, Song, Nie, Yanhe, Zeng, Huihui, Qu, Xiaoxiao, Xu, Bing, Zhang, Chuanxiang, Yu, Jianglong, Won Hong, Suck
• Format: Article
• Language: English
• Subjects: Carbon nanotubes; Catalysis; Growth mechanism; Microplastics removal; Nanotubes, Carbon - chemistry; Nickel - chemistry; Plastics - chemistry; Polyethylene - chemistry; Pyrolysis; Recycling - methods; Waste plastics
• ISSN: 0956-053X; 1879-2456; 1879-2456
• DOI: 10.1016/j.wasman.2024.08.005

[Display omitted] •Fe/Ni ratio and temperature have great influenced on the structure of CNTs.•DFT calculations are used to study the growth mechanism of CNTs.•The feasibility and mechanism of PVC removal by CNTs are investigated. Plastic waste pollution is the serious environmental problem, and catalytic pyrolysis of waste plastics is an effective way to solve this problem. Carbon nanotubes (CNTs) are prepared by catalytic pyrolysis of low-density polyethylene (LDPE) waste plastics by one-stage method using iron nitrate and nickel nitrate as catalyst. The growth mechanism of CNTs is analyzed in detail. TPO, XRD, SEM and Raman analyses show that increasing Ni content contributes to the production of CNTs with good morphology and high graphitization degree. While the increasing Fe content contributes to improving the yield of CNTs. The outer and inner diameters of the FeNi12-CNTs-800 are about 21 nm and 8 nm with the length of 18.9 μm, respectively. LDPE pyrolysis gases are analyzed to determine that the primary carbon source required for CNTs growth is C2H4. The C2H4 adsorption and decomposition processes on FeNi alloys are performed to reveal the growth mechanism of CNTs, based on density functional theory calculation. Three kinds of the growth models are proposed to explain the difference of the CNTs tubular shape. FeNi12-CNTs-800 are used to remove microplastics from wastewater due to existence of magnetic. PVC can be quickly removed from wastewater with removal of 100 % at 20 min. This study provides an effective way for recycling and treatment of waste plastic.