On the Occurrence of Domain Boundaries and Defects in Self-Organized Ordered Porous Anodic Alumina Systems

• Published in: The journal of physical chemistry letters 2024-08, Vol.15 (34), p.8608-8612
• Main Authors: Heinschke, Silvio, Schneider, Jörg J.
• Format: Article
• Language: English
• Subjects: Physical Insights into Chemistry, Catalysis, and Interfaces
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.4c01776

The formation of domains and defects is a part of every self-organized structure without prepatterning which evolves from the electrochemical oxidation of valve metals like Ti, Al or Ta. Defects and domains, especially in highly ordered porous alumina films (PAOX), are one of the most studied phenomena in the current literature. The focus is on understanding their formation in order to find parameters to minimize their amount for applications that require the most highly organized structures. In this letter we give a solution to this problem by showing that the occurrence of defects and domains is an unavoidable consequence of the underlying self-organized process due to the simultaneous impact of the minimum (MINEP) and maximum (MAXEP) entropy production principle. As a consequence, experimental procedures to manufacture defect-free PAOX-films from a self-organization process face a fundamental limitation.