Biodegradable, Strong, and Hydrophobic Regenerated Cellulose Films Enriched with Esterified Lignin Nanoparticles

• Published in: Small (Weinheim an der Bergstrasse, Germany) Germany), 2024-08, Vol.20 (33), p.e2309651-n/a
• Main Authors: Tian, Rui, Wang, Chao, Jiang, Weikun, Janaswamy, Srinivas, Yang, Guihua, Ji, Xingxiang, Lyu, Gaojin
• Format: Article
• Language: English
• Subjects: Cellulose; Cellulose esters; Cellulosic resins; composite films; Contact angle; Esterification; Hydrophobicity; Lignin; lignin nanoparticles; Mechanical properties; multifunction; Nanoparticles; Optical properties; Soil moisture; Soil permeability; Tensile strength; Thermal stability; Water absorption; Water vapor
• ISSN: 1613-6810; 1613-6829; 1613-6829
• DOI: 10.1002/smll.202309651

The scientific community is pursuing significant efforts worldwide to develop environmentally viable film materials from biomass, particularly transparent, high‐performance regenerated cellulose (RC) films, to replace traditional plastics. However, the inferior mechanical performance and hydrophilic nature of RC films are generally not suitable for use as a substitute for plastics in practical applications. Herein, lignin homogenization is used to synthesize high‐performance composite films. The esterified lignin nanoparticles (ELNPs) with dispersible and binding advantages are prepared through esterification and nanometrization. In the presence of ELNPs, RC films exhibit a higher tensile strength (110.4 MPa), hydrophobic nature (103.6° water contact angle, 36.6% water absorption at 120 min, and 1.127 × 10−12 g cm cm−2 s−1 Pa−1 water vapor permeability), and exciting optical properties (high visible and low ultraviolet transmittance). The films further display antioxidant activity, oxygen barrier ability, and thermostability. The films completely biodegrade at 12 and 30% soil moisture. Overall, this study offers new insights into lignin valorization and regenerated cellulose composite films as novel bioplastic materials. The aliphatic side chains of ELNPs are an effective and efficient strategy, compared to LNPs, in promoting synergistic interactions and enhancing the regenerated cellulose films with higher tensile strength, hydrophobic nature, and more exciting optical properties. Moreover, the addition of 5% ELNPs is optimal, otherwise, the excess will cause its aggregation.