Functionalization of Crystalline Colloidal Arrays through Click Chemistry

The preparation of well‐defined and regioselectively functionalized ordered colloidal particles through the exploitation of ‘click' transformations is presented; specifically, the copper(I)‐catalyzed Huisgen 1,3‐dipolar cycloaddition between azides and terminal alkynes to form 1,2,3‐triazoles i...

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Bibliographic Details
Published in:Advanced materials (Weinheim) 2007-11, Vol.19 (21), p.3507-3512
Main Authors: Evanoff Jr, D. D., Hayes, S. E., Ying, Y., Shim, G. H., Lawrence, J. R., Carroll, J. B., Roeder, R. D., Houchins, J. M., Huebner, C. F., Foulger, S. H.
Format: Article
Language:English
Subjects:
colloidal
Colloids
Photonic crystals
Photonic crystals, colloidal
Self-assembly
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Summary:The preparation of well‐defined and regioselectively functionalized ordered colloidal particles through the exploitation of ‘click' transformations is presented; specifically, the copper(I)‐catalyzed Huisgen 1,3‐dipolar cycloaddition between azides and terminal alkynes to form 1,2,3‐triazoles is utilized. This approach is demonstrated through the attachment of 9‐azidomethylanthracene to post‐hydrogel stabilized, ordered poly(propargyl acrylate) colloidal particles.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200602901