Gold nanoparticles obtained by Au(III) reduction with Sn(II): Preparation and electrocatalytic properties in oxidation of reducing agents

• Published in: Electrochimica acta 2007-12, Vol.53 (2), p.407-416
• Main Authors: VASKELIS, Algirdas, TAROZAITE, Rima, JAGMINIENE, Aldona, TARNASAUSKAITE TAMASIUNAITE, Loreta, JUSKENAS, Remigijus, KURTINAITIENE, Marija
• Format: Article
• Language: English
• Subjects: Anodic oxidation; Applied sciences; Borohydride; Corrosion; Corrosion mechanisms; Dimethylamine borane; Exact sciences and technology; Formaldehyde; Glassy carbon; Gold nanoparticles; Hydrazine; Metals. Metallurgy
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2007.04.008

Gold colloid solutions were prepared by reduction of Au(III) with Sn(II) in both acidic (HCl) and alkaline (carbonate) media, and characterized by electron microscopy, X-ray diffraction and light absorption spectra. Depending on the colloid preparation conditions, metal particles of 5–30 nm in size were obtained. Light absorption spectra of the Au colloid solutions contain an absorption band at 500–600 nm, typical of small gold particles. According to XRD data, colloid particles contain the metallic Au and SnO 2 phases. The colloid formation rate and colloid solution stability depend on solution pH; the alkaline colloid solutions are formed more slowly and are more stable. The gold nanoparticles adsorbed on the dielectrics surface were found to initiate the electroless copper deposition process. The glassy carbon (GC) electrode modified by Au nanoparticles (200–900 ng cm −2 Au) was found to be an electrocatalyst for dimethylamine borane, borohydride, hydrazine, and formaldehyde oxidation in alkaline solutions. The activity of the reducers can be arranged as follows: DMAB > NaBH 4 > N 2H 4 > CH 2O.