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Photoinduced Deoxygenative C2 Arylation of Quinoline N‐oxides with Phenylhydrazines to 2‐Arylquinolines over Porous Tubular Graphitic Carbon Nitride Semiconductor Photocatalyst
The photo‐induced deoxygenative C2 arylation of quinoline N‐oxides to 2‐arylquinolines is achieved over a heterogeneous porous tubular graphitic carbon nitride (PTCN) catalyst with phenylhydrazines as arylation reagent. A wide range of quinoline N‐oxides can be efficiently transformed into their cor...
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| Published in: | Chemistry : a European journal 2024-11, Vol.30 (66), p.e202402662-n/a |
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| container_issue | 66 |
| container_start_page | e202402662 |
| container_title | Chemistry : a European journal |
| container_volume | 30 |
| creator | Zhang, Wenjie Xu, Hang Huang, Zezhao Hu, Yan Luo, Lin Zhu, Li Yao, Xiaoquan |
| description | The photo‐induced deoxygenative C2 arylation of quinoline N‐oxides to 2‐arylquinolines is achieved over a heterogeneous porous tubular graphitic carbon nitride (PTCN) catalyst with phenylhydrazines as arylation reagent. A wide range of quinoline N‐oxides can be efficiently transformed into their corresponding 2‐arylquinolines under visible light irradiation. Moreover, PTCN catalyst is easily separated and could be reused several times without loss to its original activity.
By using porous tubular graphitic carbon nitride (PTCN) as recyclable heterogeneous catalyst and arylhydrazines as cheap and commercially available arylation reagent, a novel photoinduced deoxygenative C2 arylation of quinoline N‐oxides to 2‐arylquinolines was developed successfully. |
| doi_str_mv | 10.1002/chem.202402662 |
| format | article |
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By using porous tubular graphitic carbon nitride (PTCN) as recyclable heterogeneous catalyst and arylhydrazines as cheap and commercially available arylation reagent, a novel photoinduced deoxygenative C2 arylation of quinoline N‐oxides to 2‐arylquinolines was developed successfully.</description><identifier>ISSN: 0947-6539</identifier><identifier>ISSN: 1521-3765</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.202402662</identifier><identifier>PMID: 39166710</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Carbon ; Carbon nitride ; Catalysts ; Deoxygenation ; Deoxygenative C2 arylation ; Irradiation ; Light irradiation ; Oxides ; Phenylhydrazines ; Photocatalysis ; Porous tubular graphitic carbon nitride ; Quinoline ; Quinoline N-oxides ; Reagents</subject><ispartof>Chemistry : a European journal, 2024-11, Vol.30 (66), p.e202402662-n/a</ispartof><rights>2024 Wiley-VCH GmbH</rights><rights>2024 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2582-6aed0ee8d66d43da7d8953e6aabb0a068e9801f970fb6f081725613649fcff703</cites><orcidid>0000-0003-4713-3276 ; 0000-0003-3589-1475</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39166710$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Wenjie</creatorcontrib><creatorcontrib>Xu, Hang</creatorcontrib><creatorcontrib>Huang, Zezhao</creatorcontrib><creatorcontrib>Hu, Yan</creatorcontrib><creatorcontrib>Luo, Lin</creatorcontrib><creatorcontrib>Zhu, Li</creatorcontrib><creatorcontrib>Yao, Xiaoquan</creatorcontrib><title>Photoinduced Deoxygenative C2 Arylation of Quinoline N‐oxides with Phenylhydrazines to 2‐Arylquinolines over Porous Tubular Graphitic Carbon Nitride Semiconductor Photocatalyst</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>The photo‐induced deoxygenative C2 arylation of quinoline N‐oxides to 2‐arylquinolines is achieved over a heterogeneous porous tubular graphitic carbon nitride (PTCN) catalyst with phenylhydrazines as arylation reagent. A wide range of quinoline N‐oxides can be efficiently transformed into their corresponding 2‐arylquinolines under visible light irradiation. Moreover, PTCN catalyst is easily separated and could be reused several times without loss to its original activity.
By using porous tubular graphitic carbon nitride (PTCN) as recyclable heterogeneous catalyst and arylhydrazines as cheap and commercially available arylation reagent, a novel photoinduced deoxygenative C2 arylation of quinoline N‐oxides to 2‐arylquinolines was developed successfully.</description><subject>Carbon</subject><subject>Carbon nitride</subject><subject>Catalysts</subject><subject>Deoxygenation</subject><subject>Deoxygenative C2 arylation</subject><subject>Irradiation</subject><subject>Light irradiation</subject><subject>Oxides</subject><subject>Phenylhydrazines</subject><subject>Photocatalysis</subject><subject>Porous tubular graphitic carbon nitride</subject><subject>Quinoline</subject><subject>Quinoline N-oxides</subject><subject>Reagents</subject><issn>0947-6539</issn><issn>1521-3765</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhS0EokNhyxJZYsMmg38mdrysQmmRShlEWUdOfENcJfHUdtqGFY_Aw_BEPAmOpi0SG1bWlb9z7rk6CL2kZE0JYW-bDoY1I2xDmBDsEVrRnNGMS5E_RiuiNjITOVcH6FkIl4QQJTh_ig64okJISlbo17Zz0dnRTA0Y_A7c7fwNRh3tNeCS4SM_92lwI3Yt_jzZ0fV2BHz--8dPd2sNBHxjY4e3HYxz383G6-_pP-DoMEvMIr-6VwXsrsHjrfNuCvhiqqdee3zi9a6z0Ta41L5Oi85t9MkZf4HBNm4JFl1SLTEbHXU_h_gcPWl1H-DF3XuIvr4_vihPs7NPJx_Ko7OsYXnBMqHBEIDCCGE23GhpCpVzEFrXNdFEFKAKQlslSVuLlhRUslxQLjaqbdpWEn6I3ux9d95dTRBiNdjQQN_rEdINFScqF1LmkiX09T_opZv8mNJVnHImJc8lTdR6TzXeheChrXbeDtrPFSXV0me19Fk99JkEr-5sp3oA84DfF5gAtQdubA_zf-yq8vT441_zPygVsss</recordid><startdate>20241126</startdate><enddate>20241126</enddate><creator>Zhang, Wenjie</creator><creator>Xu, Hang</creator><creator>Huang, Zezhao</creator><creator>Hu, Yan</creator><creator>Luo, Lin</creator><creator>Zhu, Li</creator><creator>Yao, Xiaoquan</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-4713-3276</orcidid><orcidid>https://orcid.org/0000-0003-3589-1475</orcidid></search><sort><creationdate>20241126</creationdate><title>Photoinduced Deoxygenative C2 Arylation of Quinoline N‐oxides with Phenylhydrazines to 2‐Arylquinolines over Porous Tubular Graphitic Carbon Nitride Semiconductor Photocatalyst</title><author>Zhang, Wenjie ; Xu, Hang ; Huang, Zezhao ; Hu, Yan ; Luo, Lin ; Zhu, Li ; Yao, Xiaoquan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2582-6aed0ee8d66d43da7d8953e6aabb0a068e9801f970fb6f081725613649fcff703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Carbon</topic><topic>Carbon nitride</topic><topic>Catalysts</topic><topic>Deoxygenation</topic><topic>Deoxygenative C2 arylation</topic><topic>Irradiation</topic><topic>Light irradiation</topic><topic>Oxides</topic><topic>Phenylhydrazines</topic><topic>Photocatalysis</topic><topic>Porous tubular graphitic carbon nitride</topic><topic>Quinoline</topic><topic>Quinoline N-oxides</topic><topic>Reagents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Wenjie</creatorcontrib><creatorcontrib>Xu, Hang</creatorcontrib><creatorcontrib>Huang, Zezhao</creatorcontrib><creatorcontrib>Hu, Yan</creatorcontrib><creatorcontrib>Luo, Lin</creatorcontrib><creatorcontrib>Zhu, Li</creatorcontrib><creatorcontrib>Yao, Xiaoquan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Wenjie</au><au>Xu, Hang</au><au>Huang, Zezhao</au><au>Hu, Yan</au><au>Luo, Lin</au><au>Zhu, Li</au><au>Yao, Xiaoquan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photoinduced Deoxygenative C2 Arylation of Quinoline N‐oxides with Phenylhydrazines to 2‐Arylquinolines over Porous Tubular Graphitic Carbon Nitride Semiconductor Photocatalyst</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2024-11-26</date><risdate>2024</risdate><volume>30</volume><issue>66</issue><spage>e202402662</spage><epage>n/a</epage><pages>e202402662-n/a</pages><issn>0947-6539</issn><issn>1521-3765</issn><eissn>1521-3765</eissn><abstract>The photo‐induced deoxygenative C2 arylation of quinoline N‐oxides to 2‐arylquinolines is achieved over a heterogeneous porous tubular graphitic carbon nitride (PTCN) catalyst with phenylhydrazines as arylation reagent. A wide range of quinoline N‐oxides can be efficiently transformed into their corresponding 2‐arylquinolines under visible light irradiation. Moreover, PTCN catalyst is easily separated and could be reused several times without loss to its original activity.
By using porous tubular graphitic carbon nitride (PTCN) as recyclable heterogeneous catalyst and arylhydrazines as cheap and commercially available arylation reagent, a novel photoinduced deoxygenative C2 arylation of quinoline N‐oxides to 2‐arylquinolines was developed successfully.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>39166710</pmid><doi>10.1002/chem.202402662</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-4713-3276</orcidid><orcidid>https://orcid.org/0000-0003-3589-1475</orcidid></addata></record> |
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| subjects | Carbon Carbon nitride Catalysts Deoxygenation Deoxygenative C2 arylation Irradiation Light irradiation Oxides Phenylhydrazines Photocatalysis Porous tubular graphitic carbon nitride Quinoline Quinoline N-oxides Reagents |
| title | Photoinduced Deoxygenative C2 Arylation of Quinoline N‐oxides with Phenylhydrazines to 2‐Arylquinolines over Porous Tubular Graphitic Carbon Nitride Semiconductor Photocatalyst |
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