High-Performance Nanofiltration Membrane with Dual Resistance to Gypsum Scaling and Biofouling for Enhanced Water Purification

• Published in: Environmental science & technology 2024-09, Vol.58 (37), p.16656-16668
• Main Authors: Zheng, Fuxin, Zhang, Hao, Boo, Chanhee, Wang, Mengmeng, Tan, Junjun, Ye, Shuji, Lin, Shihong, Wang, Yunkun
• Format: Article
• Language: English
• Subjects: Ammonium; Ammonium compounds; Biofouling; Calcium Sulfate - chemistry; Cations; Contaminants; Electronegativity; Filtration; Gypsum; Membranes; Membranes, Artificial; Microporosity; Nanofiltration; Nanotechnology; Nylons - chemistry; Organic contaminants; Physico-Chemical Treatment and Resource Recovery; Polyamide resins; Polyamides; Polycondensation reactions; Quaternary ammonium compounds; Quaternary ammonium salts; Thickness; Thin films; Water purification; Water Purification - methods
• ISSN: 0013-936X; 1520-5851; 1520-5851
• DOI: 10.1021/acs.est.4c07334

Nanofiltration (NF) technology is pivotal for ensuring a sustainable and reliable supply of clean water. To address the critical need for advanced thin-film composite (TFC) polyamide (PA) membranes with exceptional permselectivity and fouling resistance for emerging contaminant purification, we introduce a novel high-performance NF membrane. This membrane features a selective polypiperazine (PIP) layer functionalized with amino-containing quaternary ammonium compounds (QACs) through an in situ interfacial polycondensation reaction. Our investigation demonstrated that precise QAC functionalization enabled the construction of the selective PA layer with increased surface area, enhanced microporosity, stronger electronegativity, and reduced thickness compared to the control PIP membrane. As a result, the QAC NF membrane exhibited an approximately 51% increase in water permeance compared to the control PIP membrane, while achieving superior retention capabilities for divalent salts (>99%) and emerging organic contaminants (>90%). Furthermore, the incorporation of QACs into the PIP selective layer was proved to be effective in mitigating mineral scaling by allowing selective passage of scale-forming cations, while simultaneously exhibiting strong antimicrobial properties to combat biofouling. The in situ QAC incorporation strategy presented in this study provides valuable guidelines for the fit-for-purpose design of the selective PA layer, which is crucial for the development of high-performance NF membranes for efficient water purification.