Synthesis of Diaryl Ethers via Hypervalent Iodine-Mediated C–H Functionalization

A hypervalent iodine-reagent-based C–H functionalization strategy was utilized to synthesize diaryl ethers. This method directly transforms various arenes into their corresponding diaryliodonium salts, followed by a C–O coupling reaction to produce structurally diverse diaryl ethers. The efficacy of...

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Bibliographic Details
Published in:Organic letters 2024-09, Vol.26 (37), p.7864-7868
Main Authors: Hu, Chenghu, Jia, Qi, Bao, Wenjing, Gu, Guangxing, Li, Ya, Zhao, Yanchuan
Format: Article
Language:English
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Summary:A hypervalent iodine-reagent-based C–H functionalization strategy was utilized to synthesize diaryl ethers. This method directly transforms various arenes into their corresponding diaryliodonium salts, followed by a C–O coupling reaction to produce structurally diverse diaryl ethers. The efficacy of this approach in the late-stage structural modifications of complex molecules was demonstrated.
ISSN:1523-7060
1523-7052
1523-7052
DOI:10.1021/acs.orglett.4c02703