Topological control in paddlewheel metal-organic cages via ligand length variation

Varying the length of phenanthrene-derived ligands switches the selective assembly of MIInL metal-organic cages (MOCs, = 6 or 8) between tetrahedral, square, or triangular architectures. The limit of this approach is explored for both Cu and Rh paddlewheel MOCs, and supported by solution, solid-stat...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-11, Vol.60 (90), p.13183-13186
Main Authors: Tsoukatos, Steven, Maibam, Ashakiran, Babarao, Ravichandar, Bloch, Witold M
Format: Article
Language:English
Subjects:
Cages
Ligands
Phenanthrene
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Summary:Varying the length of phenanthrene-derived ligands switches the selective assembly of MIInL metal-organic cages (MOCs, = 6 or 8) between tetrahedral, square, or triangular architectures. The limit of this approach is explored for both Cu and Rh paddlewheel MOCs, and supported by solution, solid-state and computational analysis.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc03769c