Maleic anhydride esterified potato starch as the binder in silicon nanoparticles anode for lithium-ion batteries

• Published in: International journal of biological macromolecules 2024-11, Vol.281 (Pt 2), p.136407, Article 136407
• Main Authors: Petrus, Himawan Tri Bayu Murti, Daulay, Amru, Astuti, Widi, Supriyatna, Yayat Iman, Kurniawan, Ade, Yuwono, Akhmad Herman, Maulana, Fakhri Akbar
• Format: Article
• Language: English
• Subjects: Coal fly ash; Dry method; Electric Power Supplies; Electrodes; Ions - chemistry; Lithium - chemistry; Maleic Anhydrides - chemistry; Nanoparticles - chemistry; Natural carbohydrate; Silicon - chemistry; Solanum tuberosum - chemistry; Spectroscopy, Fourier Transform Infrared; Starch - chemistry
• ISSN: 0141-8130; 1879-0003; 1879-0003
• DOI: 10.1016/j.ijbiomac.2024.136407

Potato starch is a natural carbohydrate binder. Starch has hydroxyl groups that can promote interaction with silicon particles using multifaceted hydrogen bonds. Maleic anhydride esterified potato starch can produce a binder that maintains the cycle stability of lithium-ion batteries. Fourier-transform infrared spectroscopy spectra show wavelengths of 1776 cm−1 and 1855 cm−1. Thermal gravimetric analysis curves decreased in weight percent by 80 % at 286 °C. Carbon-13 nuclear magnetic resonance spectra show high peaks at 3.37 ppm, 3.65 ppm, 4.56 ppm, 5.09 ppm, and 6.22 ppm. Scanning electron microscope images show that the morphological change in esterified starch was due to the increased length of starch and the maleic anhydride grafted onto the starch granules. The cyclic voltammetry curve shows that the reduction peak is around 0.16 V, and the oxidation peak is around 0.38 V and 0.56 V. Nyquist plots show a small half circle, indicating that the electrode's solid-electrolyte interphase layer is low. The cycling performance shows a capacity of 1950 mAh/g.