Moisture sorption isotherm and thermodynamic analysis of egg powders dried by foam‐mat‐assisted refractance window drying

• Published in: Journal of the science of food and agriculture 2024-11, Vol.104 (14), p.8646-8654
• Main Authors: Arslan‐Tontul, Sultan, Gunisik, Ayse, Tontul, Ismail
• Format: Article
• Language: English
• Subjects: Adsorption; Animals; Bound water; Chickens; Desiccation - methods; Drying; egg powder; Egg White - chemistry; Egg Yolk - chemistry; Eggs - analysis; Energy levels; entropy; Food Handling - methods; Food Preservation - methods; Free energy; Gibbs free energy; Humidity; Information processing; isosteric heat; Isotherms; Moisture content; Monolayers; Powder; Powders - chemistry; refractance window drying; Relative humidity; Sorption; Spoilage; Temperature; Temperature requirements; Thermodynamic properties; Thermodynamics; Water - chemistry; Water activity; Water content; Yolk
• ISSN: 0022-5142; 1097-0010; 1097-0010
• DOI: 10.1002/jsfa.13692

BACKGROUND In the designed study, the moisture sorption isotherm and thermodynamic properties of refractance‐window‐dried egg white powder (EWP), egg yolk powder (EYP) and whole egg powder (WEP) were determined. RESULTS The adsorption isotherm of egg powders was classified as type II, giving a sigmoidal shape. Peleg showed the highest goodness of fitting for egg powder. The monolayer moisture content of egg powders varied between 0.02 and 0.09 g g−1. According to the thermodynamic analysis, an increase in moisture content led to a decrease in net isosteric heat of sorption (qst), and the highest decrease was observed in EWP. The qst of EWP was calculated as 18 637 kJ mol−1, while it decreased to 3104 kJ mol−1 at 0.2 g g−1 moisture content. Like qst, sorption entropy decreased from 52.07 to 7.14 J mol−1 K−1 with increasing water activity (aw) for EWP. Increasing temperature caused a decrease in spreading pressure and was higher in EWP samples. Increasing moisture content and temperature also decreased Gibbs free energy level. CONCLUSION Moisture sorption isotherm (MSI) is used to predict the amount of bound water in a material at a specific relative humidity and temperature. To inhibit chemical and microbiological spoilage, the drying process must continue until the monolayer moisture content is reached. In this study, the monolayer moisture content of powdered eggs for safe storage was demonstrated by MSI. Additionally, by determining the thermodynamic functions of egg powder, valuable information was obtained related to predicting the energy requirement in drying processes. © 2024 Society of Chemical Industry.