Synthesis and Photochemical Properties of Heterometallic Ti–Cu Ring Clusters Constructed from Myo-Inositol Ligand

Incorporating heterometals into titanium–oxygen clusters represents an effective approach to adjusting the band gap and absorption properties. Herein, a family of heterometallic Ti–Cu clusters was synthesized under solvothermal conditions. The unique structural feature of these clusters is the forma...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry 2024-10, Vol.63 (43), p.20398-20403
Main Authors: Liu, Li, Zhang, Xinyu, Fu, Yaomei, Zhao, Liang, Zhang, Yuanyuan, Qin, Chao, Su, Zhongmin
Format: Article
Language:English
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-a299t-6b873f94d406a63882d2a2865d58f6aeb54e3cd2a03a23e07c6722d93900067f3
container_end_page 20403
container_issue 43
container_start_page 20398
container_title Inorganic chemistry
container_volume 63
creator Liu, Li
Zhang, Xinyu
Fu, Yaomei
Zhao, Liang
Zhang, Yuanyuan
Qin, Chao
Su, Zhongmin
description Incorporating heterometals into titanium–oxygen clusters represents an effective approach to adjusting the band gap and absorption properties. Herein, a family of heterometallic Ti–Cu clusters was synthesized under solvothermal conditions. The unique structural feature of these clusters is the formation of ring clusters with myo-inositol ligands serving as structure-directing ligands. The myo-inositol ligand, as a typical polyol ligand, demonstrates flexible and distinctive coordination modes capable of chelating up to eight transition metal ions simultaneously. Compounds 4 and 5 show significant absorption in the visible region, indicating that the incorporation of Cu ions can efficiently tune the band gap of titanium–oxygen clusters.
doi_str_mv 10.1021/acs.inorgchem.4c02741
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_3116675678</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3116675678</sourcerecordid><originalsourceid>FETCH-LOGICAL-a299t-6b873f94d406a63882d2a2865d58f6aeb54e3cd2a03a23e07c6722d93900067f3</originalsourceid><addsrcrecordid>eNqFkE1u2zAQRokgReK6OUILLrORyx-JkpaBkNQGXNRoXSA7gaZGNg1JdDjUwrvcoTfsSUrDTrZdkSDf9w3mEfKZsxlngn_VBmd2cH5rdtDPUsNEnvIrMuGZYEnG2fM1mTAW71yp8pZ8RNwzxkqZqhtyK8uUcVbwCcFfxyHsAC1SPTR0tXPBnRqt0R1deXcAHywgdS2dQwDvegi666yha_v39U810p922NKqGzH-Iq3cgMGPJkBD20jT70eXLAaHNriOLu02TvlEPrS6Q7i7nFPy--lxXc2T5Y9vi-phmWhRliFRmyKXbZk2KVNayaIQjdCiUFmTFa3SsMlSkCa-MamFBJYblQvRlLKMi6q8lVNyf-49ePcyAoa6t2ig6_QAbsRa8ugmz1ReRDQ7o8Y7RA9tffC21_5Yc1affNfRd_3uu774jrkvlxHjpofmPfUmOAL8DJzyezf6IW78n9J_xDaSrA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3116675678</pqid></control><display><type>article</type><title>Synthesis and Photochemical Properties of Heterometallic Ti–Cu Ring Clusters Constructed from Myo-Inositol Ligand</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Liu, Li ; Zhang, Xinyu ; Fu, Yaomei ; Zhao, Liang ; Zhang, Yuanyuan ; Qin, Chao ; Su, Zhongmin</creator><creatorcontrib>Liu, Li ; Zhang, Xinyu ; Fu, Yaomei ; Zhao, Liang ; Zhang, Yuanyuan ; Qin, Chao ; Su, Zhongmin</creatorcontrib><description>Incorporating heterometals into titanium–oxygen clusters represents an effective approach to adjusting the band gap and absorption properties. Herein, a family of heterometallic Ti–Cu clusters was synthesized under solvothermal conditions. The unique structural feature of these clusters is the formation of ring clusters with myo-inositol ligands serving as structure-directing ligands. The myo-inositol ligand, as a typical polyol ligand, demonstrates flexible and distinctive coordination modes capable of chelating up to eight transition metal ions simultaneously. Compounds 4 and 5 show significant absorption in the visible region, indicating that the incorporation of Cu ions can efficiently tune the band gap of titanium–oxygen clusters.</description><identifier>ISSN: 0020-1669</identifier><identifier>ISSN: 1520-510X</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.4c02741</identifier><identifier>PMID: 39401081</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Inorganic chemistry, 2024-10, Vol.63 (43), p.20398-20403</ispartof><rights>2024 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-a299t-6b873f94d406a63882d2a2865d58f6aeb54e3cd2a03a23e07c6722d93900067f3</cites><orcidid>0000-0002-2436-8198 ; 0000-0001-7139-1094 ; 0000-0002-3342-1966</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27898,27899</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39401081$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Li</creatorcontrib><creatorcontrib>Zhang, Xinyu</creatorcontrib><creatorcontrib>Fu, Yaomei</creatorcontrib><creatorcontrib>Zhao, Liang</creatorcontrib><creatorcontrib>Zhang, Yuanyuan</creatorcontrib><creatorcontrib>Qin, Chao</creatorcontrib><creatorcontrib>Su, Zhongmin</creatorcontrib><title>Synthesis and Photochemical Properties of Heterometallic Ti–Cu Ring Clusters Constructed from Myo-Inositol Ligand</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>Incorporating heterometals into titanium–oxygen clusters represents an effective approach to adjusting the band gap and absorption properties. Herein, a family of heterometallic Ti–Cu clusters was synthesized under solvothermal conditions. The unique structural feature of these clusters is the formation of ring clusters with myo-inositol ligands serving as structure-directing ligands. The myo-inositol ligand, as a typical polyol ligand, demonstrates flexible and distinctive coordination modes capable of chelating up to eight transition metal ions simultaneously. Compounds 4 and 5 show significant absorption in the visible region, indicating that the incorporation of Cu ions can efficiently tune the band gap of titanium–oxygen clusters.</description><issn>0020-1669</issn><issn>1520-510X</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkE1u2zAQRokgReK6OUILLrORyx-JkpaBkNQGXNRoXSA7gaZGNg1JdDjUwrvcoTfsSUrDTrZdkSDf9w3mEfKZsxlngn_VBmd2cH5rdtDPUsNEnvIrMuGZYEnG2fM1mTAW71yp8pZ8RNwzxkqZqhtyK8uUcVbwCcFfxyHsAC1SPTR0tXPBnRqt0R1deXcAHywgdS2dQwDvegi666yha_v39U810p922NKqGzH-Iq3cgMGPJkBD20jT70eXLAaHNriOLu02TvlEPrS6Q7i7nFPy--lxXc2T5Y9vi-phmWhRliFRmyKXbZk2KVNayaIQjdCiUFmTFa3SsMlSkCa-MamFBJYblQvRlLKMi6q8lVNyf-49ePcyAoa6t2ig6_QAbsRa8ugmz1ReRDQ7o8Y7RA9tffC21_5Yc1affNfRd_3uu774jrkvlxHjpofmPfUmOAL8DJzyezf6IW78n9J_xDaSrA</recordid><startdate>20241028</startdate><enddate>20241028</enddate><creator>Liu, Li</creator><creator>Zhang, Xinyu</creator><creator>Fu, Yaomei</creator><creator>Zhao, Liang</creator><creator>Zhang, Yuanyuan</creator><creator>Qin, Chao</creator><creator>Su, Zhongmin</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-2436-8198</orcidid><orcidid>https://orcid.org/0000-0001-7139-1094</orcidid><orcidid>https://orcid.org/0000-0002-3342-1966</orcidid></search><sort><creationdate>20241028</creationdate><title>Synthesis and Photochemical Properties of Heterometallic Ti–Cu Ring Clusters Constructed from Myo-Inositol Ligand</title><author>Liu, Li ; Zhang, Xinyu ; Fu, Yaomei ; Zhao, Liang ; Zhang, Yuanyuan ; Qin, Chao ; Su, Zhongmin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a299t-6b873f94d406a63882d2a2865d58f6aeb54e3cd2a03a23e07c6722d93900067f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Li</creatorcontrib><creatorcontrib>Zhang, Xinyu</creatorcontrib><creatorcontrib>Fu, Yaomei</creatorcontrib><creatorcontrib>Zhao, Liang</creatorcontrib><creatorcontrib>Zhang, Yuanyuan</creatorcontrib><creatorcontrib>Qin, Chao</creatorcontrib><creatorcontrib>Su, Zhongmin</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Li</au><au>Zhang, Xinyu</au><au>Fu, Yaomei</au><au>Zhao, Liang</au><au>Zhang, Yuanyuan</au><au>Qin, Chao</au><au>Su, Zhongmin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Photochemical Properties of Heterometallic Ti–Cu Ring Clusters Constructed from Myo-Inositol Ligand</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2024-10-28</date><risdate>2024</risdate><volume>63</volume><issue>43</issue><spage>20398</spage><epage>20403</epage><pages>20398-20403</pages><issn>0020-1669</issn><issn>1520-510X</issn><eissn>1520-510X</eissn><abstract>Incorporating heterometals into titanium–oxygen clusters represents an effective approach to adjusting the band gap and absorption properties. Herein, a family of heterometallic Ti–Cu clusters was synthesized under solvothermal conditions. The unique structural feature of these clusters is the formation of ring clusters with myo-inositol ligands serving as structure-directing ligands. The myo-inositol ligand, as a typical polyol ligand, demonstrates flexible and distinctive coordination modes capable of chelating up to eight transition metal ions simultaneously. Compounds 4 and 5 show significant absorption in the visible region, indicating that the incorporation of Cu ions can efficiently tune the band gap of titanium–oxygen clusters.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>39401081</pmid><doi>10.1021/acs.inorgchem.4c02741</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-2436-8198</orcidid><orcidid>https://orcid.org/0000-0001-7139-1094</orcidid><orcidid>https://orcid.org/0000-0002-3342-1966</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0020-1669
ispartof Inorganic chemistry, 2024-10, Vol.63 (43), p.20398-20403
issn 0020-1669
1520-510X
1520-510X
language eng
recordid cdi_proquest_miscellaneous_3116675678
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
title Synthesis and Photochemical Properties of Heterometallic Ti–Cu Ring Clusters Constructed from Myo-Inositol Ligand
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-03-04T10%3A02%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20Photochemical%20Properties%20of%20Heterometallic%20Ti%E2%80%93Cu%20Ring%20Clusters%20Constructed%20from%20Myo-Inositol%20Ligand&rft.jtitle=Inorganic%20chemistry&rft.au=Liu,%20Li&rft.date=2024-10-28&rft.volume=63&rft.issue=43&rft.spage=20398&rft.epage=20403&rft.pages=20398-20403&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/acs.inorgchem.4c02741&rft_dat=%3Cproquest_cross%3E3116675678%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a299t-6b873f94d406a63882d2a2865d58f6aeb54e3cd2a03a23e07c6722d93900067f3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=3116675678&rft_id=info:pmid/39401081&rfr_iscdi=true