Approach for quality deep-ultraviolet nonlinear optical crystals via a substitution strategy of channel species in zeolite

Exploring the connections between the ion substitution of a material, its crystal structure, and its performance in applications is a regular task in synthetic chemistry. However, there still remain major challenges in the substitution of polyanionic groups for single ions. Herein, a strategy of cha...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2024-10, Vol.53 (42), p.17151-17156
Main Authors: Liu, Mingfeng, Mi, Jin-Xiao, Zhang, Yinggan, Wang, Shuaihua, Wu, Shaofan, Huang, Ya-Xi
Format: Article
Language:English
Subjects:
Crystal structure
Materials substitution
Nonlinear optics
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Summary:Exploring the connections between the ion substitution of a material, its crystal structure, and its performance in applications is a regular task in synthetic chemistry. However, there still remain major challenges in the substitution of polyanionic groups for single ions. Herein, a strategy of channel species substitution of single anions by polyanionic groups in a zeotype rigid framework to design a new deep-ultraviolet nonlinear zincophosphate, {[Li Na (SiF )]Cs }[(ZnPO ) ], and tune physicochemical properties was proposed.
ISSN:1477-9226
1477-9234
1477-9234
DOI:10.1039/d4dt02629b