One ligand, two roles: novel pillar-layered metal-organic frameworks built with a 3D ligand and asymmetric inorganic nodes

Herein, we show two cases of pillar-layered MOFs which are built solely with one kind of three-dimensional (3D) ditopic ligand. The ligand in both structures functions not only as an intralayer linker in the layer but also as a "pillar" between adjacent layers. Such multi-functionality of...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2024-10, Vol.53 (42), p.17146-1715
Main Authors: Xue, Chaozhuang, Zhang, Yingying, Zhu, Kai, Deng, Suyun, Qu, Konggang, Gong, Shuwen, Yang, Huajun
Format: Article
Language:English
Subjects:
Asymmetry
Ligands
Metal-organic frameworks
Nodes
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Summary:Herein, we show two cases of pillar-layered MOFs which are built solely with one kind of three-dimensional (3D) ditopic ligand. The ligand in both structures functions not only as an intralayer linker in the layer but also as a "pillar" between adjacent layers. Such multi-functionality of the linker is accompanied by uncommon asymmetric 10- c metal hexamer or 7- c tetramer nodes, which have never been reported in previous 3D MOF structures. Binary pillar-layered MOF structures built with one ligand and asymmetric inorganic cluster nodes.
ISSN:1477-9226
1477-9234
1477-9234
DOI:10.1039/d4dt02061h