Photoluminescent ruthenium() bipyridyl complexes containing phosphonium ylide ligands

A P-ylide Ru( ii ) bipyridyl complex was readily synthetized and fully characterized, constituing one of the rare examples of photoluminescent metal ylide complexes. Its photophysical and redox properties have been compared with those of related NHC and cyclometalated Ru complexes and exploited in v...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-11, Vol.6 (92), p.1362-1365
Main Authors: Fayafrou, Oussama, Lognon, Elise, Duhayon, Carine, Sortais, Jean-Baptiste, Monari, Antonio, Baslé, Olivier, Canac, Yves
Format: Article
Language:English
Subjects:
Chemical Sciences
Coordination chemistry
Photoluminescence
Ruthenium compounds
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Summary:A P-ylide Ru( ii ) bipyridyl complex was readily synthetized and fully characterized, constituing one of the rare examples of photoluminescent metal ylide complexes. Its photophysical and redox properties have been compared with those of related NHC and cyclometalated Ru complexes and exploited in visible-light photocatalyzed SET and EnT processes. An unprecedented photoluminescent phosphonium ylide Ru( ii ) bipyridyl complex was reported to be active in visible-light photocatalyzed single electron and energy transfer processes.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc05050a