Photoluminescent ruthenium() bipyridyl complexes containing phosphonium ylide ligands

A P-ylide Ru( ii ) bipyridyl complex was readily synthetized and fully characterized, constituing one of the rare examples of photoluminescent metal ylide complexes. Its photophysical and redox properties have been compared with those of related NHC and cyclometalated Ru complexes and exploited in v...

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Published in:Chemical communications (Cambridge, England) England), 2024-11, Vol.6 (92), p.1362-1365
Main Authors: Fayafrou, Oussama, Lognon, Elise, Duhayon, Carine, Sortais, Jean-Baptiste, Monari, Antonio, Baslé, Olivier, Canac, Yves
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Language:English
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Chemical Sciences
Coordination chemistry
Photoluminescence
Ruthenium compounds
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container_issue 92
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container_title Chemical communications (Cambridge, England)
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creator Fayafrou, Oussama
Lognon, Elise
Duhayon, Carine
Sortais, Jean-Baptiste
Monari, Antonio
Baslé, Olivier
Canac, Yves
description A P-ylide Ru( ii ) bipyridyl complex was readily synthetized and fully characterized, constituing one of the rare examples of photoluminescent metal ylide complexes. Its photophysical and redox properties have been compared with those of related NHC and cyclometalated Ru complexes and exploited in visible-light photocatalyzed SET and EnT processes. An unprecedented photoluminescent phosphonium ylide Ru( ii ) bipyridyl complex was reported to be active in visible-light photocatalyzed single electron and energy transfer processes.
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subjects Chemical Sciences
Coordination chemistry
Photoluminescence
Ruthenium compounds
title Photoluminescent ruthenium() bipyridyl complexes containing phosphonium ylide ligands
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