Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid (CH3)3NOH2CoCl4

The hybrid metal halide [(CH3)3NOH]2CoCl4 exhibits a first-order phase transition at T ∼ 343 K. Its crystal structure and caloric properties respond significantly to moderate pressures (1-1000 bar), demonstrating potential for applications in emerging solid-state refrigeration technologies.The hybri...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-11, Vol.60 (95), p.14065
Main Authors: Dafonte-Rodríguez, Pedro, Delgado-Ferreiro, Ignacio, García-Ben, Javier, Ferradanes-Martínez, Angel, Gelpi, María, Walker, Julian, McMonagle, Charles James, Castro-García, Socorro, Señarís-Rodríguez, María Antonia, Bermúdez-García, Juan Manuel, Sánchez-Andújar, Manuel
Format: Article
Language:English
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Summary:The hybrid metal halide [(CH3)3NOH]2CoCl4 exhibits a first-order phase transition at T ∼ 343 K. Its crystal structure and caloric properties respond significantly to moderate pressures (1-1000 bar), demonstrating potential for applications in emerging solid-state refrigeration technologies.The hybrid metal halide [(CH3)3NOH]2CoCl4 exhibits a first-order phase transition at T ∼ 343 K. Its crystal structure and caloric properties respond significantly to moderate pressures (1-1000 bar), demonstrating potential for applications in emerging solid-state refrigeration technologies.
ISSN:1364-548X
1364-548X
DOI:10.1039/d4cc05125d