Two-Dimensional CNPs Superstructures Derived from Metal–Organic Frameworks for Electromagnetic Wave Absorption

Carbon nanoparticles (CNPs) derived from metal–organic frameworks (ZIF-8) are synthesized, which are further self-assembled into mono- or bilayer superstructures for electromagnetic (EM) wave absorption. Furthermore, the effect of ZIF-8 morphology (cubic or rhombic dodecahedral) on the superstructur...

Full description

Saved in:
Bibliographic Details
Published in:ACS applied materials & interfaces 2024-11, Vol.16 (47), p.65173-65184
Main Authors: Liu, Zequn, Zhao, Honghong, Yao, Junru, Liang, Minjie, Sun, Youyi, Gu, Ning, Cao, Yang
Format: Article
Language:English
Subjects:
Functional Nanostructured Materials (including low-D carbon)
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-a215t-1960c3b4db0a6b25964271a27397e474dbba681a04a43926a642449cef9d23333
container_end_page 65184
container_issue 47
container_start_page 65173
container_title ACS applied materials & interfaces
container_volume 16
creator Liu, Zequn
Zhao, Honghong
Yao, Junru
Liang, Minjie
Sun, Youyi
Gu, Ning
Cao, Yang
description Carbon nanoparticles (CNPs) derived from metal–organic frameworks (ZIF-8) are synthesized, which are further self-assembled into mono- or bilayer superstructures for electromagnetic (EM) wave absorption. Furthermore, the effect of ZIF-8 morphology (cubic or rhombic dodecahedral) on the superstructure and EM absorption performance of CNPs is investigated. The as-prepared cubic bilayer superstructure exhibits a higher BET surface area of 526.1 m2/g and a higher pore volume of 0.232 cm3/g than the rhombic dodecahedral monolayer superstructure (30.0 m2/g and 0.051 cm3/g, respectively). As a result, the two-dimensional CNPs with a bilayer structure are able to deliver the highest EM absorption performance with an effective absorption bandwidth of 6.2 GHz at a thickness of merely 2.4 mm. This work provides a new approach to designing and preparing high-performance EM wave absorption materials.
doi_str_mv 10.1021/acsami.4c14804
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_3129681840</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3129681840</sourcerecordid><originalsourceid>FETCH-LOGICAL-a215t-1960c3b4db0a6b25964271a27397e474dbba681a04a43926a642449cef9d23333</originalsourceid><addsrcrecordid>eNp1kE1LxDAQhoMorl9Xj5KjCF2TNG03R9ldP8AvUPFYpul06do2NWkVb_4H_6G_xEjXvTmXDJln3oGHkEPOxpwJfgraQV2OpeZywuQG2eFKymAiIrG57qUckV3nlozFoWDRNhmFKoq4UmyHtI_vJpiVNTauNA1UdHp77-hD36J1ne1111t0dIa2fMOcFtbU9AY7qL4_v-7sAppS03MLNb4b--JoYSydV6g7z8Giwc6Pn-EN6VnmjG07f2KfbBVQOTxYvXvk6Xz-OL0Mru8urqZn1wEIHnUBVzHTYSbzjEGciUjFUiQcRBKqBGXi_zOIJxyYBBkqEYOfS6k0FioXoa89cjzktta89ui6tC6dxqqCBk3v0pAL5QMmknl0PKDaGucsFmlryxrsR8pZ-ms5HSynK8t-4WiV3Wc15mv8T6sHTgbAL6ZL01tv1v2X9gPM_okS</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3129681840</pqid></control><display><type>article</type><title>Two-Dimensional CNPs Superstructures Derived from Metal–Organic Frameworks for Electromagnetic Wave Absorption</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Liu, Zequn ; Zhao, Honghong ; Yao, Junru ; Liang, Minjie ; Sun, Youyi ; Gu, Ning ; Cao, Yang</creator><creatorcontrib>Liu, Zequn ; Zhao, Honghong ; Yao, Junru ; Liang, Minjie ; Sun, Youyi ; Gu, Ning ; Cao, Yang</creatorcontrib><description>Carbon nanoparticles (CNPs) derived from metal–organic frameworks (ZIF-8) are synthesized, which are further self-assembled into mono- or bilayer superstructures for electromagnetic (EM) wave absorption. Furthermore, the effect of ZIF-8 morphology (cubic or rhombic dodecahedral) on the superstructure and EM absorption performance of CNPs is investigated. The as-prepared cubic bilayer superstructure exhibits a higher BET surface area of 526.1 m2/g and a higher pore volume of 0.232 cm3/g than the rhombic dodecahedral monolayer superstructure (30.0 m2/g and 0.051 cm3/g, respectively). As a result, the two-dimensional CNPs with a bilayer structure are able to deliver the highest EM absorption performance with an effective absorption bandwidth of 6.2 GHz at a thickness of merely 2.4 mm. This work provides a new approach to designing and preparing high-performance EM wave absorption materials.</description><identifier>ISSN: 1944-8244</identifier><identifier>ISSN: 1944-8252</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.4c14804</identifier><identifier>PMID: 39551990</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Functional Nanostructured Materials (including low-D carbon)</subject><ispartof>ACS applied materials &amp; interfaces, 2024-11, Vol.16 (47), p.65173-65184</ispartof><rights>2024 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-a215t-1960c3b4db0a6b25964271a27397e474dbba681a04a43926a642449cef9d23333</cites><orcidid>0000-0003-2736-275X ; 0009-0007-6953-5491 ; 0009-0003-0895-9654</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39551990$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Zequn</creatorcontrib><creatorcontrib>Zhao, Honghong</creatorcontrib><creatorcontrib>Yao, Junru</creatorcontrib><creatorcontrib>Liang, Minjie</creatorcontrib><creatorcontrib>Sun, Youyi</creatorcontrib><creatorcontrib>Gu, Ning</creatorcontrib><creatorcontrib>Cao, Yang</creatorcontrib><title>Two-Dimensional CNPs Superstructures Derived from Metal–Organic Frameworks for Electromagnetic Wave Absorption</title><title>ACS applied materials &amp; interfaces</title><addtitle>ACS Appl. Mater. Interfaces</addtitle><description>Carbon nanoparticles (CNPs) derived from metal–organic frameworks (ZIF-8) are synthesized, which are further self-assembled into mono- or bilayer superstructures for electromagnetic (EM) wave absorption. Furthermore, the effect of ZIF-8 morphology (cubic or rhombic dodecahedral) on the superstructure and EM absorption performance of CNPs is investigated. The as-prepared cubic bilayer superstructure exhibits a higher BET surface area of 526.1 m2/g and a higher pore volume of 0.232 cm3/g than the rhombic dodecahedral monolayer superstructure (30.0 m2/g and 0.051 cm3/g, respectively). As a result, the two-dimensional CNPs with a bilayer structure are able to deliver the highest EM absorption performance with an effective absorption bandwidth of 6.2 GHz at a thickness of merely 2.4 mm. This work provides a new approach to designing and preparing high-performance EM wave absorption materials.</description><subject>Functional Nanostructured Materials (including low-D carbon)</subject><issn>1944-8244</issn><issn>1944-8252</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMorl9Xj5KjCF2TNG03R9ldP8AvUPFYpul06do2NWkVb_4H_6G_xEjXvTmXDJln3oGHkEPOxpwJfgraQV2OpeZywuQG2eFKymAiIrG57qUckV3nlozFoWDRNhmFKoq4UmyHtI_vJpiVNTauNA1UdHp77-hD36J1ne1111t0dIa2fMOcFtbU9AY7qL4_v-7sAppS03MLNb4b--JoYSydV6g7z8Giwc6Pn-EN6VnmjG07f2KfbBVQOTxYvXvk6Xz-OL0Mru8urqZn1wEIHnUBVzHTYSbzjEGciUjFUiQcRBKqBGXi_zOIJxyYBBkqEYOfS6k0FioXoa89cjzktta89ui6tC6dxqqCBk3v0pAL5QMmknl0PKDaGucsFmlryxrsR8pZ-ms5HSynK8t-4WiV3Wc15mv8T6sHTgbAL6ZL01tv1v2X9gPM_okS</recordid><startdate>20241127</startdate><enddate>20241127</enddate><creator>Liu, Zequn</creator><creator>Zhao, Honghong</creator><creator>Yao, Junru</creator><creator>Liang, Minjie</creator><creator>Sun, Youyi</creator><creator>Gu, Ning</creator><creator>Cao, Yang</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2736-275X</orcidid><orcidid>https://orcid.org/0009-0007-6953-5491</orcidid><orcidid>https://orcid.org/0009-0003-0895-9654</orcidid></search><sort><creationdate>20241127</creationdate><title>Two-Dimensional CNPs Superstructures Derived from Metal–Organic Frameworks for Electromagnetic Wave Absorption</title><author>Liu, Zequn ; Zhao, Honghong ; Yao, Junru ; Liang, Minjie ; Sun, Youyi ; Gu, Ning ; Cao, Yang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a215t-1960c3b4db0a6b25964271a27397e474dbba681a04a43926a642449cef9d23333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Functional Nanostructured Materials (including low-D carbon)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Zequn</creatorcontrib><creatorcontrib>Zhao, Honghong</creatorcontrib><creatorcontrib>Yao, Junru</creatorcontrib><creatorcontrib>Liang, Minjie</creatorcontrib><creatorcontrib>Sun, Youyi</creatorcontrib><creatorcontrib>Gu, Ning</creatorcontrib><creatorcontrib>Cao, Yang</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ACS applied materials &amp; interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Zequn</au><au>Zhao, Honghong</au><au>Yao, Junru</au><au>Liang, Minjie</au><au>Sun, Youyi</au><au>Gu, Ning</au><au>Cao, Yang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Two-Dimensional CNPs Superstructures Derived from Metal–Organic Frameworks for Electromagnetic Wave Absorption</atitle><jtitle>ACS applied materials &amp; interfaces</jtitle><addtitle>ACS Appl. Mater. Interfaces</addtitle><date>2024-11-27</date><risdate>2024</risdate><volume>16</volume><issue>47</issue><spage>65173</spage><epage>65184</epage><pages>65173-65184</pages><issn>1944-8244</issn><issn>1944-8252</issn><eissn>1944-8252</eissn><abstract>Carbon nanoparticles (CNPs) derived from metal–organic frameworks (ZIF-8) are synthesized, which are further self-assembled into mono- or bilayer superstructures for electromagnetic (EM) wave absorption. Furthermore, the effect of ZIF-8 morphology (cubic or rhombic dodecahedral) on the superstructure and EM absorption performance of CNPs is investigated. The as-prepared cubic bilayer superstructure exhibits a higher BET surface area of 526.1 m2/g and a higher pore volume of 0.232 cm3/g than the rhombic dodecahedral monolayer superstructure (30.0 m2/g and 0.051 cm3/g, respectively). As a result, the two-dimensional CNPs with a bilayer structure are able to deliver the highest EM absorption performance with an effective absorption bandwidth of 6.2 GHz at a thickness of merely 2.4 mm. This work provides a new approach to designing and preparing high-performance EM wave absorption materials.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>39551990</pmid><doi>10.1021/acsami.4c14804</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-2736-275X</orcidid><orcidid>https://orcid.org/0009-0007-6953-5491</orcidid><orcidid>https://orcid.org/0009-0003-0895-9654</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1944-8244
ispartof ACS applied materials & interfaces, 2024-11, Vol.16 (47), p.65173-65184
issn 1944-8244
1944-8252
1944-8252
language eng
recordid cdi_proquest_miscellaneous_3129681840
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Functional Nanostructured Materials (including low-D carbon)
title Two-Dimensional CNPs Superstructures Derived from Metal–Organic Frameworks for Electromagnetic Wave Absorption
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T10%3A18%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Two-Dimensional%20CNPs%20Superstructures%20Derived%20from%20Metal%E2%80%93Organic%20Frameworks%20for%20Electromagnetic%20Wave%20Absorption&rft.jtitle=ACS%20applied%20materials%20&%20interfaces&rft.au=Liu,%20Zequn&rft.date=2024-11-27&rft.volume=16&rft.issue=47&rft.spage=65173&rft.epage=65184&rft.pages=65173-65184&rft.issn=1944-8244&rft.eissn=1944-8252&rft_id=info:doi/10.1021/acsami.4c14804&rft_dat=%3Cproquest_cross%3E3129681840%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a215t-1960c3b4db0a6b25964271a27397e474dbba681a04a43926a642449cef9d23333%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=3129681840&rft_id=info:pmid/39551990&rfr_iscdi=true