Removal of cadmium ions from synthetic wastewater samples by copper ferrite magnetic nanoparticle–assisted batch-type adsorption-based removal strategy

• Published in: Environmental monitoring and assessment 2024-12, Vol.196 (12), p.1210, Article 1210
• Main Authors: Zaman, Buse Tuğba, Akbıyık, Hilal, Girgin, Ayça, Bozyiğit, Gamze Dalgıç, Bakırdere, Emine Gülhan, Bakırdere, Sezgin
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Anthropogenic factors; Aquatic environment; Atmospheric Protection/Air Quality Control/Air Pollution; Atomic absorption spectrophotometry; Cadmium; Cadmium - analysis; Cadmium - chemistry; Copper - analysis; Copper - chemistry; Copper ferrite; Drinking water; Earth and Environmental Science; Ecology; Ecotoxicology; Electron microscopy; Emission analysis; Environment; Environmental Management; Ferric Compounds - chemistry; Field emission microscopy; Food contamination; Food sources; Groundwater; Industrial areas; Ions; Magnetic properties; Magnetite Nanoparticles - chemistry; Monitoring/Environmental Analysis; Nanomaterials; Nanoparticles; Scanning electron microscopy; Soil contamination; Soil pollution; Soil water; Spectral analysis; Spectrophotometry; Waste Disposal, Fluid - methods; Wastewater; Wastewater - chemistry; Water Pollutants, Chemical - analysis; Water Pollutants, Chemical - chemistry; Water Purification - methods; Water sampling; X-ray diffraction
• ISSN: 0167-6369; 1573-2959; 1573-2959
• DOI: 10.1007/s10661-024-13408-1

Industrial activities can release a variety of harmful substances, including organic and inorganic components, into the environment. Inadequate treatment and discharge of these pollutants into aquatic environments might have adverse effects. Cadmium (Cd) is a toxic element found in various environmental sources, both anthropogenic and geogenic, which can contaminate soils and groundwater crucial for providing healthy food and safe drinking water. This study aimed to develop a novel strategy by the help of nano-sized adsorbents to remove cadmium ions from wastewater through batch-type adsorption processes. CuFe 2 O 4 nanoparticles having high magnetic properties were synthesized using a co-precipitation process for the efficient removal of analyte. Characterization of the nanomaterial was performed using field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) analysis. Method effective parameters were systematically optimized through univariate experiments to find proper conditions for the improvement of interaction between the adsorbent and cadmium ions. Removal efficiency (%RE) of Cd was assessed by using synthetic wastewater samples, and the accuracy/practicability of the recommended method proved highly efficient within the linear range of flame atomic absorption spectrophotometry (FAAS). In addition, the Langmuir isotherm model was applied to the experimental data, and the effective adsorption of cadmium from synthetic wastewater by the magnetic CuFe 2 O 4 nanoparticles was proved.