Circularly Polarized Phosphorescence Properties of Binuclear Cyclometalated Platinum(II) Complexes Bearing Axially Chiral Schiff-Base Ligands

• Published in: Inorganic chemistry 2024-12, Vol.63 (50), p.23642-23650
• Main Authors: Ikeshita, Masahiro, Shimizu, Itsuki, Watanabe, Shinya, Yamada, Tomoki, Suzuki, Seika, Tanaka, Shota, Hattori, Shingo, Shinozaki, Kazuteru, Imai, Yoshitane, Tsuno, Takashi
• Format: Article
• Language: English
• ISSN: 0020-1669; 1520-510X; 1520-510X
• DOI: 10.1021/acs.inorgchem.4c03675

The synthesis, structure, and circularly polarized phosphorescence (CPP) properties of axially chiral cyclometalated binuclear platinum­(II) complexes were described. A series of optically pure binuclear platinum­(II) complexes were synthesized in five steps from commercially available (R)- or (S)-1,1′-bi-2-naphthol (BINOL) as starting materials. Their three-dimensional molecular structures and square-planar coordination geometries were elucidated from X-ray diffraction and 2D NMR analysis. The complexes were found to exhibit red- to near-infrared photoluminescence in solution and in the solid state. Furthermore, dilute DMSO solutions of the enantiopure samples showed red CPP with relatively high luminescence dissymmetry factor (g lum) values. Density functional theory (DFT) calculations were conducted to examine their three-dimensional molecular conformations and photophysical properties.